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4,R-ajmalicine N-oxide

CAS# 41590-29-8

4,R-ajmalicine N-oxide

Catalog No. BCN5473----Order now to get a substantial discount!

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Quality Control of 4,R-ajmalicine N-oxide

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Chemical structure

4,R-ajmalicine N-oxide

3D structure

Chemical Properties of 4,R-ajmalicine N-oxide

Cas No. 41590-29-8 SDF Download SDF
PubChem ID 91895268 Appearance Powder
Formula C21H24N2O4 M.Wt 368.4
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name methyl (1S,15R,16S,20S)-16-methyl-13-oxido-17-oxa-3-aza-13-azoniapentacyclo[11.8.0.02,10.04,9.015,20]henicosa-2(10),4,6,8,18-pentaene-19-carboxylate
SMILES CC1C2C[N+]3(CCC4=C(C3CC2C(=CO1)C(=O)OC)NC5=CC=CC=C45)[O-]
Standard InChIKey FEPWCBNZAPJQDK-PBYQAJJJSA-N
Standard InChI InChI=1S/C21H24N2O4/c1-12-16-10-23(25)8-7-14-13-5-3-4-6-18(13)22-20(14)19(23)9-15(16)17(11-27-12)21(24)26-2/h3-6,11-12,15-16,19,22H,7-10H2,1-2H3/t12-,15-,16+,19-,23?/m0/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of 4,R-ajmalicine N-oxide

The herbs of Catharanthus roseus

Biological Activity of 4,R-ajmalicine N-oxide

DescriptionStandard reference

Protocol of 4,R-ajmalicine N-oxide

Structure Identification
Tetrahedron,1972,28(24):5971-5975.

Structure and synthesis of new natural heteroyohimbine N-oxides[Reference: WebLink]


METHODS AND RESULTS:
Natural 4,R-akuammigine N-oxide, (1) 4,S-akuammigine N-oxide, (2) and 4,R-tetrahydroalstonine N-oxide (3) have been isolated from species of Uncaria. (Rubiaceae). Their stereochemistry has been established from NMR spectra. Synthesis of 1,2,3 and of 4,R-ajmalicine N-oxide and 4,R-3-isoajmalicine N-oxide by peracid oxidation of the bases is described.

4,R-ajmalicine N-oxide Dilution Calculator

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4,R-ajmalicine N-oxide Molarity Calculator

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Preparing Stock Solutions of 4,R-ajmalicine N-oxide

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.7144 mL 13.5722 mL 27.1444 mL 54.2888 mL 67.861 mL
5 mM 0.5429 mL 2.7144 mL 5.4289 mL 10.8578 mL 13.5722 mL
10 mM 0.2714 mL 1.3572 mL 2.7144 mL 5.4289 mL 6.7861 mL
50 mM 0.0543 mL 0.2714 mL 0.5429 mL 1.0858 mL 1.3572 mL
100 mM 0.0271 mL 0.1357 mL 0.2714 mL 0.5429 mL 0.6786 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 4,R-ajmalicine N-oxide

Structure and synthesis of new natural heteroyohimbine N-oxides

Tetrahedron Volume 28, Issue 24, 1972, Pages 5971-5975.

Natural 4,R-akuammigine N-oxide, (1) 4,S-akuammigine N-oxide, (2) and 4,R-tetrahydroalstonine N-oxide (3) have been isolated from species of Uncaria. (Rubiaceae). Their stereochemistry has been established from NMR spectra. Synthesis of 1,2,3 and of 4,R-ajmalicine N-oxide and 4,R-3-isoajmalicine N-oxide by peracid oxidation of the bases is described.

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