Nerylacetate

CAS# 141-12-8

Nerylacetate

Catalog No. BCN3802----Order now to get a substantial discount!

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Nerylacetate: 5mg $23 In Stock
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Quality Control of Nerylacetate

Number of papers citing our products

Chemical structure

Nerylacetate

3D structure

Chemical Properties of Nerylacetate

Cas No. 141-12-8 SDF Download SDF
PubChem ID 1549025 Appearance Oil
Formula C12H20O2 M.Wt 196.3
Type of Compound Monoterpenoids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name [(2Z)-3,7-dimethylocta-2,6-dienyl] acetate
SMILES CC(=CCCC(=CCOC(=O)C)C)C
Standard InChIKey HIGQPQRQIQDZMP-FLIBITNWSA-N
Standard InChI InChI=1S/C12H20O2/c1-10(2)6-5-7-11(3)8-9-14-12(4)13/h6,8H,5,7,9H2,1-4H3/b11-8-
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of Nerylacetate

From kumquat

Biological Activity of Nerylacetate

DescriptionNerylacetate and 1,5-dienes geranyl acetate are catalyzed to the cis-2,5-bis(hydroxymethyl)tetrahydrofurans 3 and 4 by OsO4.

Protocol of Nerylacetate

Structure Identification
Tetrahedron Letters, 1998 , 39 (52) :9781-4.

OsO4-Catalyzed oxidative cyclization of geranyl and neryl acetate to cis-2,5-bis(hydroxymethyl)tetrahydrofurans[Reference: WebLink]


METHODS AND RESULTS:
OsO4 catalyzes the oxidative cyclization of the 1,5-dienes geranyl acetate (1) and Nerylacetate (2) to the cis-2,5-bis(hydroxymethyl)tetrahydrofurans 3 and 4 respectively, in the presence of NaIO4 as cooxidant in DMF. The reaction is stereospecific and proceeds with the sequential syn addition to both double bonds of the starting materials. The observed stereoselectivity can be explained by invoking the intermediacy of a square-based pyramidal osmium (VI) diester (5) that has been isolated and characterized.
CONCLUSIONS:
Evidence is reported that this substance is indeed an intermediate in the transformation of 1 to 3.

Nerylacetate Dilution Calculator

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Nerylacetate Molarity Calculator

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Preparing Stock Solutions of Nerylacetate

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 5.0942 mL 25.4712 mL 50.9424 mL 101.8849 mL 127.3561 mL
5 mM 1.0188 mL 5.0942 mL 10.1885 mL 20.377 mL 25.4712 mL
10 mM 0.5094 mL 2.5471 mL 5.0942 mL 10.1885 mL 12.7356 mL
50 mM 0.1019 mL 0.5094 mL 1.0188 mL 2.0377 mL 2.5471 mL
100 mM 0.0509 mL 0.2547 mL 0.5094 mL 1.0188 mL 1.2736 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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Description

Neryl acetate is a chemical compound isolated from citrus oils.

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