1-Phenyloctane

CAS# 2189-60-8

1-Phenyloctane

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Quality Control of 1-Phenyloctane

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Chemical structure

1-Phenyloctane

3D structure

Chemical Properties of 1-Phenyloctane

Cas No. 2189-60-8 SDF Download SDF
PubChem ID 16607 Appearance Oil
Formula C14H22 M.Wt 190.32
Type of Compound Miscellaneous Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name octylbenzene
SMILES CCCCCCCCC1=CC=CC=C1
Standard InChIKey CDKDZKXSXLNROY-UHFFFAOYSA-N
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Biological Activity of 1-Phenyloctane

Description1-Phenyloctane, 1-phenyldecane, 1-methylnaphthalene, and 2-methylnaphthalene, are four potential laser-induced fluorescence (LIF) tracers for diesel engine applications.
In vitro

Characterization of four potential laser-induced fluorescence tracers for diesel engine applications.[Pubmed: 24513750]

Appl Opt. 2013 Nov 20;52(33):8001-7.


METHODS AND RESULTS:
Four potential laser-induced fluorescence (LIF) tracers, 1-Phenyloctane, 1-phenyldecane, 1-methylnaphthalene, and 2-methylnaphthalene, are characterized for diesel engine applications. These tracers, embedded in the diesel primary reference fuels n-C₁₆H₃₄ and iso-C₁₆H₃₄, match the relevant physical properties of commercial diesel fuel much better than the commonly used toluene/iso-octane/n-heptane tracer-fuel system does. The temperature and pressure dependencies of the fluorescence intensities and spectra were measured in a flow cell in nitrogen for each candidate tracer molecule. The results show that the signal intensities of the methylnaphthalenes are about two orders of magnitude higher than for 1-Phenyloctane and 1-phenyldecane and show a strong temperature but no pressure, dependence.
CONCLUSIONS:
An analysis of the fluorescence spectrum of 1-methylnaphthalene shows that it also can be used for two-color detection LIF thermometry by choosing appropriate optical filters.

Protocol of 1-Phenyloctane

Structure Identification
Chem Commun (Camb). 2014 Sep 18;50(72):10456-9.

Comparative STM studies of mixed ligand monolayers on gold nanoparticles in air and in 1-phenyloctane.[Pubmed: 25068154]

Scanning tunnelling microscopy (STM) studies have found stripe-like domains on gold nanoparticles (NPs) coated with certain binary mixtures of ligand molecules. The majority of these NPs' properties have been investigated for particles in solvents. Yet, most STM studies are for NPs in a dry state. Images of the same particles in air and liquid have not been obtained yet.
METHODS AND RESULTS:
In this work, a judicious choice of ligand molecules led to NPs with close-to-ideal STM imaging conditions in air and in 1-Phenyloctane (PO). Large datasets under both conditions were acquired and rapidly evaluated through power spectral density (PSD) analysis.
CONCLUSIONS:
The result is a quantitative comparison of stripe-like domains in air and PO on the same NPs. PSD analysis determines a characteristic length-scale for these domains of ~1.0 nm in air and in PO showing persistence of striped domains in these two media. A length scale of ~0.7 nm for homoligand NPs was found.

Chirality. 2012 Feb;24(2):155-66.

Organization of the enantiomeric and racemic forms of an amphiphilic resorcinol derivative at the air-water and graphite-1-phenyloctane interfaces.[Pubmed: 22180286]

This article describes a study of the outcome of racemate condensation in different types of monolayers.
METHODS AND RESULTS:
The study was performed on a resorcinol surfactant bearing an octadecyl chain and a lactate group which formed a monolayer at the interface of graphite and 1-Phenyloctane as well as a Langmuir film at the air-water interface. Control experiments with the enantiopure materials provided the characteristics of the chiral organizations. The results obtained on the racemate show that on graphite the molecule forms chiral domains, indicating that spontaneous resolution takes place at the surface, a phenomenon that has been rationalized using molecular modeling. The X-ray crystal structure of the DMSO solvate of one of the enantiomers shows a similar type of packing to this monolayer. On the other hand, in the Langmuir layer it appears that the formation of a racemic compound is favoured, as it is in the solid state in three dimensions.
CONCLUSIONS:
The work shows how the symmetry restrictions in different environments can have a critical influence on the outcome of racemate organization, and underline the tendency of graphite to favour symmetry breaking in monolayers formed at its surface.

1-Phenyloctane Dilution Calculator

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1-Phenyloctane Molarity Calculator

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Preparing Stock Solutions of 1-Phenyloctane

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 5.2543 mL 26.2715 mL 52.5431 mL 105.0862 mL 131.3577 mL
5 mM 1.0509 mL 5.2543 mL 10.5086 mL 21.0172 mL 26.2715 mL
10 mM 0.5254 mL 2.6272 mL 5.2543 mL 10.5086 mL 13.1358 mL
50 mM 0.1051 mL 0.5254 mL 1.0509 mL 2.1017 mL 2.6272 mL
100 mM 0.0525 mL 0.2627 mL 0.5254 mL 1.0509 mL 1.3136 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 1-Phenyloctane

Characterization of four potential laser-induced fluorescence tracers for diesel engine applications.[Pubmed:24513750]

Appl Opt. 2013 Nov 20;52(33):8001-7.

Four potential laser-induced fluorescence (LIF) tracers, 1-Phenyloctane, 1-phenyldecane, 1-methylnaphthalene, and 2-methylnaphthalene, are characterized for diesel engine applications. These tracers, embedded in the diesel primary reference fuels n-C(1)(6)H(3)(4) and iso-C(1)(6)H(3)(4), match the relevant physical properties of commercial diesel fuel much better than the commonly used toluene/iso-octane/n-heptane tracer-fuel system does. The temperature and pressure dependencies of the fluorescence intensities and spectra were measured in a flow cell in nitrogen for each candidate tracer molecule. The results show that the signal intensities of the methylnaphthalenes are about two orders of magnitude higher than for 1-Phenyloctane and 1-phenyldecane and show a strong temperature but no pressure, dependence. An analysis of the fluorescence spectrum of 1-methylnaphthalene shows that it also can be used for two-color detection LIF thermometry by choosing appropriate optical filters.

Comparative STM studies of mixed ligand monolayers on gold nanoparticles in air and in 1-phenyloctane.[Pubmed:25068154]

Chem Commun (Camb). 2014 Sep 18;50(72):10456-9.

Scanning tunnelling microscopy (STM) studies have found stripe-like domains on gold nanoparticles (NPs) coated with certain binary mixtures of ligand molecules. The majority of these NPs' properties have been investigated for particles in solvents. Yet, most STM studies are for NPs in a dry state. Images of the same particles in air and liquid have not been obtained yet. In this work, a judicious choice of ligand molecules led to NPs with close-to-ideal STM imaging conditions in air and in 1-Phenyloctane (PO). Large datasets under both conditions were acquired and rapidly evaluated through power spectral density (PSD) analysis. The result is a quantitative comparison of stripe-like domains in air and PO on the same NPs. PSD analysis determines a characteristic length-scale for these domains of ~1.0 nm in air and in PO showing persistence of striped domains in these two media. A length scale of ~0.7 nm for homoligand NPs was found.

Organization of the enantiomeric and racemic forms of an amphiphilic resorcinol derivative at the air-water and graphite-1-phenyloctane interfaces.[Pubmed:22180286]

Chirality. 2012 Feb;24(2):155-66.

This article describes a study of the outcome of racemate condensation in different types of monolayers. The study was performed on a resorcinol surfactant bearing an octadecyl chain and a lactate group which formed a monolayer at the interface of graphite and 1-Phenyloctane as well as a Langmuir film at the air-water interface. Control experiments with the enantiopure materials provided the characteristics of the chiral organizations. The results obtained on the racemate show that on graphite the molecule forms chiral domains, indicating that spontaneous resolution takes place at the surface, a phenomenon that has been rationalized using molecular modeling. The X-ray crystal structure of the DMSO solvate of one of the enantiomers shows a similar type of packing to this monolayer. On the other hand, in the Langmuir layer it appears that the formation of a racemic compound is favoured, as it is in the solid state in three dimensions. The work shows how the symmetry restrictions in different environments can have a critical influence on the outcome of racemate organization, and underline the tendency of graphite to favour symmetry breaking in monolayers formed at its surface.

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