CagayaninCAS# 99096-51-2 |
Quality Control & MSDS
Number of papers citing our products
Chemical structure
Cas No. | 99096-51-2 | SDF | Download SDF |
PubChem ID | N/A | Appearance | Powder |
Formula | C42H50O10 | M.Wt | 714.9 |
Type of Compound | Lignans | Storage | Desiccate at -20°C |
Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. |
Cagayanin Dilution Calculator
Cagayanin Molarity Calculator
1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
1 mM | 1.3988 mL | 6.994 mL | 13.988 mL | 27.9759 mL | 34.9699 mL |
5 mM | 0.2798 mL | 1.3988 mL | 2.7976 mL | 5.5952 mL | 6.994 mL |
10 mM | 0.1399 mL | 0.6994 mL | 1.3988 mL | 2.7976 mL | 3.497 mL |
50 mM | 0.028 mL | 0.1399 mL | 0.2798 mL | 0.5595 mL | 0.6994 mL |
100 mM | 0.014 mL | 0.0699 mL | 0.1399 mL | 0.2798 mL | 0.3497 mL |
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. |
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Stereoselective Synthesis of Highly Substituted Conjugated Dienes via Pd-Catalyzed Carbonylation of 1,3-Diynes.[Pubmed:31125143]
Angew Chem Int Ed Engl. 2019 Jul 29;58(31):10683-10687.
The stereoselective synthesis of conjugated dienes was realized for the first time via Pd-catalyzed alkoxycarbonylation of easily available 1,3-diynes. Key to success is the utilization of the specific ligand 1,1'-ferrocenediyl-bis(tert-butyl(pyridin-2-yl)phosphine) (L1), which allows this novel transformation to proceed at room temperature. A range of 1,2,3,4-tetrasubstituted conjugated dienes are obtained in this straightforward access in high yields and selectivities. The synthetic utility of the protocol is showcased in the concise synthesis of several important intermediates for construction of natural products rac-Cagayanin, rac-galbulin, rac-agastinol, and cannabisin G.
Acid-catalyzed cyclization of 2,3-dibenzylidenesuccinates: synthesis of lignans (+/-)-cagayanin and (+/-)-galbulin.[Pubmed:11735544]
J Org Chem. 2001 Dec 14;66(25):8606-11.
Acid-catalyzed cyclizations of E,E-dibenzylidenesuccinate esters have been developed as an efficient synthetic route to 1-aryl-1,2-dihydronaphthalenes. This reaction has been used in the synthesis of the naturally occurring lignans (+/-)-Cagayanin and (+/-)-galbulin.