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3,3-Dimethylacrylic acid

CAS# 541-47-9

3,3-Dimethylacrylic acid

2D Structure

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3,3-Dimethylacrylic acid: 5mg Please Inquire In Stock
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3D structure

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3,3-Dimethylacrylic acid

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Chemical Properties of 3,3-Dimethylacrylic acid

Cas No. 541-47-9 SDF Download SDF
PubChem ID 10931 Appearance Powder
Formula C5H8O2 M.Wt 100.12
Type of Compound Other NPs Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 3-methylbut-2-enoic acid
SMILES CC(=CC(=O)O)C
Standard InChIKey YYPNJNDODFVZLE-UHFFFAOYSA-N
Standard InChI InChI=1S/C5H8O2/c1-4(2)3-5(6)7/h3H,1-2H3,(H,6,7)
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

3,3-Dimethylacrylic acid Dilution Calculator

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3,3-Dimethylacrylic acid Molarity Calculator

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Preparing Stock Solutions of 3,3-Dimethylacrylic acid

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 9.988 mL 49.9401 mL 99.8801 mL 199.7603 mL 249.7004 mL
5 mM 1.9976 mL 9.988 mL 19.976 mL 39.9521 mL 49.9401 mL
10 mM 0.9988 mL 4.994 mL 9.988 mL 19.976 mL 24.97 mL
50 mM 0.1998 mL 0.9988 mL 1.9976 mL 3.9952 mL 4.994 mL
100 mM 0.0999 mL 0.4994 mL 0.9988 mL 1.9976 mL 2.497 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 3,3-Dimethylacrylic acid

Stable Conversion Chemistry-Based Lithium Metal Batteries Enabled by Hierarchical Multifunctional Polymer Electrolytes with Near-Single Ion Conduction.[Pubmed:30830705]

Angew Chem Int Ed Engl. 2019 Apr 23;58(18):6001-6006.

The low Coulombic efficiency and serious safety issues resulting from uncontrollable dendrite growth have severely impeded the practical applications of lithium (Li) metal anodes. Herein we report a stable quasi-solid-state Li metal battery by employing a hierarchical multifunctional polymer electrolyte (HMPE). This hybrid electrolyte was fabricated via in situ copolymerizing lithium 1-[3-(methacryloyloxy)propylsulfonyl]-1-(trifluoromethanesulfonyl)imide (LiMTFSI) and pentaerythritol tetraacrylate (PETEA) monomers in traditional liquid electrolyte, which is absorbed in a poly(3,3-Dimethylacrylic acid lithium) (PDAALi)-coated glass fiber membrane. The well-designed HMPE simultaneously exhibits high ionic conductivity (2.24x10(-3) S cm(-1) at 25 degrees C), near-single ion conducting behavior (Li ion transference number of 0.75), good mechanical strength and remarkable suppression for Li dendrite growth. More intriguingly, the cation permselective HMPE efficiently prevents the migration of negatively charged iodine (I) species, which provides the as-developed Li-I batteries with high capacity and long cycling stability.

Bis(acetylacetonato) dioxomolybdenum(VI) catalysed rearrangement of methylbutynol in the presence of ultrasound.[Pubmed:11233943]

Ultrason Sonochem. 1999 Mar;6(1-2):89-91.

The molybdenum (VI) catalysed rearrangement of methylbutynol was carried out under the influence of ultrasound (20 kHz). Surprisingly, 2-methylpropene (isobutene) was found as the main product. The formation of isobutene can be explained by rearrangement to prenal, oxidation to 3,3-Dimethylacrylic acid and then decarboxylation. 3,3-Dimethylacrylic acid was decarboxylated in the presence of ultrasound and a catalyst; without a catalyst or without ultrasound (at 50 degrees C) it remained unchanged.

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