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9,9-Bis(4-hydroxyphenyl)fluorene

CAS# 3236-71-3

9,9-Bis(4-hydroxyphenyl)fluorene

Catalog No. BCC8795----Order now to get a substantial discount!

Product Name & Size Price Stock
9,9-Bis(4-hydroxyphenyl)fluorene: 5mg $17 In Stock
9,9-Bis(4-hydroxyphenyl)fluorene: 10mg Please Inquire In Stock
9,9-Bis(4-hydroxyphenyl)fluorene: 20mg Please Inquire Please Inquire
9,9-Bis(4-hydroxyphenyl)fluorene: 50mg Please Inquire Please Inquire
9,9-Bis(4-hydroxyphenyl)fluorene: 100mg Please Inquire Please Inquire
9,9-Bis(4-hydroxyphenyl)fluorene: 200mg Please Inquire Please Inquire
9,9-Bis(4-hydroxyphenyl)fluorene: 500mg Please Inquire Please Inquire
9,9-Bis(4-hydroxyphenyl)fluorene: 1000mg Please Inquire Please Inquire

Quality Control of 9,9-Bis(4-hydroxyphenyl)fluorene

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Chemical structure

9,9-Bis(4-hydroxyphenyl)fluorene

3D structure

Chemical Properties of 9,9-Bis(4-hydroxyphenyl)fluorene

Cas No. 3236-71-3 SDF Download SDF
PubChem ID 76716 Appearance Powder
Formula C25H18O2 M.Wt 350.4
Type of Compound N/A Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol
SMILES C1=CC=C2C(=C1)C3=CC=CC=C3C2(C4=CC=C(C=C4)O)C5=CC=C(C=C5)O
Standard InChIKey YWFPGFJLYRKYJZ-UHFFFAOYSA-N
Standard InChI InChI=1S/C25H18O2/c26-19-13-9-17(10-14-19)25(18-11-15-20(27)16-12-18)23-7-3-1-5-21(23)22-6-2-4-8-24(22)25/h1-16,26-27H
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

9,9-Bis(4-hydroxyphenyl)fluorene Dilution Calculator

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9,9-Bis(4-hydroxyphenyl)fluorene Molarity Calculator

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Preparing Stock Solutions of 9,9-Bis(4-hydroxyphenyl)fluorene

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.8539 mL 14.2694 mL 28.5388 mL 57.0776 mL 71.347 mL
5 mM 0.5708 mL 2.8539 mL 5.7078 mL 11.4155 mL 14.2694 mL
10 mM 0.2854 mL 1.4269 mL 2.8539 mL 5.7078 mL 7.1347 mL
50 mM 0.0571 mL 0.2854 mL 0.5708 mL 1.1416 mL 1.4269 mL
100 mM 0.0285 mL 0.1427 mL 0.2854 mL 0.5708 mL 0.7135 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 9,9-Bis(4-hydroxyphenyl)fluorene

Poly(arylene ether)s containing superacid groups as proton exchange membranes.[Pubmed:20491452]

ACS Appl Mater Interfaces. 2010 Jun;2(6):1714-21.

A series of poly(arylene ether)s containing pendant superacid groups on fluorenyl groups were synthesized and their properties were investigated for fuel cell applications. Poly(arylene ether)s containing iodo groups were synthesized by the polymerization of 2,7-diiodo-9,9-Bis(4-hydroxyphenyl)fluorene with difluorinated compounds such as decafluorobiphenyl, bis(4-fluorophenyl)sulfone, and bis(4-fluorophenyl)ketone, under nucleophilic substitution conditions. The iodo groups on the fluorenyl groups were converted to perfluorosulfonic acid groups via the Ullmann coupling reaction. The degree of perfluorosulfonation was controlled to be up to 92%, which corresponds to an ion exchange capacity (IEC) of 1.52 meq/g. The ionomers yielded flexible, ductile membranes by solution casting. The ionomer membranes exhibited a characteristic hydrophilic/hydrophobic phase separation, with small interconnected hydrophilic clusters (2-3 nm), which is similar to that of the benchmark perfluorinated membrane (Nafion). The aromatic ionomers containing superacid groups showed much higher proton conductivities than those of the conventional sulfonated aromatic ionomers with similar main chain structures. Fuel cell performance with the superacidic ionomer membranes was also tested.

Synthesis and properties of sulfonated block copolymers having fluorenyl groups for fuel-cell applications.[Pubmed:20355924]

ACS Appl Mater Interfaces. 2009 Jun;1(6):1279-86.

A series of sulfonated poly(arylene ether sulfone)s (SPEs) block copolymers containing fluorenyl groups were synthesized. Bis(4-fluorophenyl)sulfone (FPS) and 2,2-bis(4-hydroxy-3,5-dimethylpheny)propane were used as comonomers for hydrophobic blocks, whereas FPS and 9,9-Bis(4-hydroxyphenyl)fluorene were used as hydrophilic blocks. Sulfonation with chlorosulfonic acid gave sulfonated block copolymers with molecular weight (M(w)) higher than 150 kDa. Proton conductivity of the SPE block copolymer with the ion exchange capacity (IEC) = 2.20 mequiv/g was 0.14 S/cm [80% relative humidity (RH)] and 0.02 S/cm (40% RH) at 80 degrees C, which is higher or comparable to that of a perfluorinated ionomer (Nafion) membrane. The longer hydrophilic and hydrophobic blocks resulted in higher water uptake and higher proton conductivity. Scanning transmission electron microscopy observation revealed that phase separation of the SPE block copolymers was more pronounced than that of the SPE random copolymers. The SPE block copolymer membranes showed higher mechanical properties than those of the random ones. With these properties, the SPE block copolymer membranes seem promising for fuel-cell applications.

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