(-)-FenchoneCAS# 7787-20-4 |
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| Cas No. | 7787-20-4 | SDF | Download SDF |
| PubChem ID | 82229 | Appearance | Light yellow liquid |
| Formula | C10H16O | M.Wt | 152.24 |
| Type of Compound | Monoterpenoids | Storage | Desiccate at -20°C |
| Solubility | Soluble in ethanol; insoluble in water | ||
| Chemical Name | (1R,4S)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-one | ||
| SMILES | CC1(C2CCC(C2)(C1=O)C)C | ||
| Standard InChIKey | LHXDLQBQYFFVNW-OIBJUYFYSA-N | ||
| Standard InChI | InChI=1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
1 Illicium sp.
(-)-Fenchone Dilution Calculator
(-)-Fenchone Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 6.5686 mL | 32.8429 mL | 65.6858 mL | 131.3715 mL | 164.2144 mL |
| 5 mM | 1.3137 mL | 6.5686 mL | 13.1372 mL | 26.2743 mL | 32.8429 mL |
| 10 mM | 0.6569 mL | 3.2843 mL | 6.5686 mL | 13.1372 mL | 16.4214 mL |
| 50 mM | 0.1314 mL | 0.6569 mL | 1.3137 mL | 2.6274 mL | 3.2843 mL |
| 100 mM | 0.0657 mL | 0.3284 mL | 0.6569 mL | 1.3137 mL | 1.6421 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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The first example of the stereoselective synthesis and crystal structure of a spirobicycloquinazolinone based on (-)-fenchone and anthranilamide.[Pubmed:31802758]
Acta Crystallogr C Struct Chem. 2019 Dec 1;75(Pt 12):1675-1680.
The possibility of a single-stage solvent-free stereoselective synthesis of a spirocyclic compound from the natural bicyclic monoterpenoid (-)-Fenchone and anthranilamide has been shown for the first time. The molecular and crystal structure of (1R,2S,4S)-1,3,3-trimethyl-1'H-spiro[bicyclo[2.2.1]heptane-2,2'-quinazolin]-4'(3' H)-one, C17H22N2O, was established by X-ray diffraction though the chirality was assumed via the known reactant connectivity and (1)H and (13)C NMR spectroscopy. It has shown that in the molecule, for steric reasons, there is an elongation of the Me2C-C(N)N bond to 1.603 (5) A. The formation of dimers via N-H...O=C hydrogen bonds with an interaction energy of 93.30 kJ mol(-1) and through cavities (33.7% of the unit-cell volume) was established in the packing of the molecules. There are no pi-stacking interactions in the structure.
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