(+)-N-MethylallosedridineCAS# 41447-16-9 |
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- (-)-N-Methylsedridine
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| Cas No. | 41447-16-9 | SDF | Download SDF |
| PubChem ID | 10888171 | Appearance | Oil |
| Formula | C9H19NO | M.Wt | 157.3 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | (2S)-1-[(2R)-1-methylpiperidin-2-yl]propan-2-ol | ||
| SMILES | CC(CC1CCCCN1C)O | ||
| Standard InChIKey | JOHKCJPJMSCFBX-DTWKUNHWSA-N | ||
| Standard InChI | InChI=1S/C9H19NO/c1-8(11)7-9-5-3-4-6-10(9)2/h8-9,11H,3-7H2,1-2H3/t8-,9+/m0/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
The herbs of Sedum sarmentosum
| Description | Standard reference |
| Structure Identification | J. Org. Chem.,1999, 64 (23), 8594–601.A New Synthesis of All Four Stereoisomers of 2-(2,3-Dihydroxypropyl)piperidine via Iterative Asymmetric Dihydroxylation To Cause Enantiomeric Enhancement. Application to Asymmetric Synthesis of Naturally Occurring Piperidine-Related Alkaloids[Reference: WebLink]
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(+)-N-Methylallosedridine Dilution Calculator
(+)-N-Methylallosedridine Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 6.3573 mL | 31.7864 mL | 63.5728 mL | 127.1456 mL | 158.932 mL |
| 5 mM | 1.2715 mL | 6.3573 mL | 12.7146 mL | 25.4291 mL | 31.7864 mL |
| 10 mM | 0.6357 mL | 3.1786 mL | 6.3573 mL | 12.7146 mL | 15.8932 mL |
| 50 mM | 0.1271 mL | 0.6357 mL | 1.2715 mL | 2.5429 mL | 3.1786 mL |
| 100 mM | 0.0636 mL | 0.3179 mL | 0.6357 mL | 1.2715 mL | 1.5893 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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A New Synthesis of All Four Stereoisomers of 2-(2,3-Dihydroxypropyl)piperidine via Iterative Asymmetric Dihydroxylation To Cause Enantiomeric Enhancement. Application to Asymmetric Synthesis of Naturally Occurring Piperidine-Related Alkaloids
J. Org. Chem., 1999, 64 (23), pp 8594–8601
Both enantiomers of 2-(2-propenyl)piperidine 1 (76−88% ee), prepared via the first asymmetric dihydroxylation (AD) of 5-hexenyl azide, underwent the second AD to provide all four of the stereoisomeric 2-(2,3-dihydroxypropyl)piperidines 2 with enantiomeric enhancement (>98% ee). An asymmetric synthesis, starting from 2, of several 2-(2-hydroxyalkyl)piperidine alkaloids [(−)-halosaline, (+)-N-Methylallosedridine, (+)-8-ethylnorlobelol, (+)-sedridine, (+)-allosedridine, (−)-allosedridine, and (+)-N-methylsedridine] and the ant defense alkaloids [(+)-tetraponerine-3 (T-3), T-4, T-7, and T-8] is demonstrated.
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