(+)-AflavazoleCAS# 133401-09-9 |
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| Cas No. | 133401-09-9 | SDF | Download SDF |
| PubChem ID | 3086633 | Appearance | Powder |
| Formula | C28H35NO2 | M.Wt | 417.59 |
| Type of Compound | Diterpenoids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| SMILES | CC1CCC(C23C1(C(CC(C2C4=C(CC3)C(=CC5=C4C6=CC=CC=C6N5)C)C)O)C)O | ||
| Standard InChIKey | CXQOHHTZVIKVEM-KOOUEZQKSA-N | ||
| Standard InChI | InChI=1S/C28H35NO2/c1-15-13-21-24(19-7-5-6-8-20(19)29-21)25-18(15)11-12-28-22(30)10-9-17(3)27(28,4)23(31)14-16(2)26(25)28/h5-8,13,16-17,22-23,26,29-31H,9-12,14H2,1-4H3/t16-,17-,22+,23-,26+,27-,28+/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
The metabolites of the sclerotia of Aspergillus flavus.
| Description | 1. Aflavazole displays significant antifeedant activity against the fungivorous beetle Carpophilus hemipterus. |
(+)-Aflavazole Dilution Calculator
(+)-Aflavazole Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 2.3947 mL | 11.9735 mL | 23.9469 mL | 47.8939 mL | 59.8673 mL |
| 5 mM | 0.4789 mL | 2.3947 mL | 4.7894 mL | 9.5788 mL | 11.9735 mL |
| 10 mM | 0.2395 mL | 1.1973 mL | 2.3947 mL | 4.7894 mL | 5.9867 mL |
| 50 mM | 0.0479 mL | 0.2395 mL | 0.4789 mL | 0.9579 mL | 1.1973 mL |
| 100 mM | 0.0239 mL | 0.1197 mL | 0.2395 mL | 0.4789 mL | 0.5987 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Total Syntheses of Aflavazole and 14-Hydroxyaflavinine.[Pubmed:27934032]
J Am Chem Soc. 2016 Dec 7;138(48):15555-15558.
The first total syntheses of aflavazole (6) and 14-hydroxyaflavinine (8), two sterically congested indole diterpenoids, were accomplished. AlI3-promoted alkyne Prins cyclization was exploited to construct their key structural motifs. An electrocyclization-aromatization sequence assembled the pentasubstituted arene of 6, and a Stille-Migita coupling furnished the tetrasubstituted olefin of 8. The benzylic and allylic C-O bonds were reductively cleaved at the late stage of the syntheses, respectively.
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