Hybridaphniphylline BCAS# 1467083-09-5 |
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| Cas No. | 1467083-09-5 | SDF | Download SDF |
| PubChem ID | 131848415 | Appearance | Powder |
| Formula | C37H47NO11 | M.Wt | 681.77 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| SMILES | CC1CN2CC3CCC4=C5C6(CCC57C3(C2CC1C7=O)C)CC4C8C69C1C(C=C(C1C(O8)OC1C(C(C(C(O1)CO)O)O)O)CO)OC9=O | ||
| Standard InChIKey | KCMKLEMDTFKPIE-NQQVWIIASA-N | ||
| Standard InChI | InChI=1S/C37H47NO11/c1-14-10-38-11-16-3-4-17-19-9-35(5-6-36(28(17)35)29(44)18(14)8-22(38)34(16,36)2)37-24-20(47-33(37)45)7-15(12-39)23(24)31(48-30(19)37)49-32-27(43)26(42)25(41)21(13-40)46-32/h7,14,16,18-27,30-32,39-43H,3-6,8-13H2,1-2H3/t14-,16-,18-,19-,20+,21-,22-,23-,24+,25-,26+,27-,30-,31+,32+,34-,35+,36+,37-/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
The dried stems and leaves of Daphniphyllum longeracemosum.
| Description | Hybridaphniphylline B is a natural product from Daphniphyllum longeracemosum. |
| Structure Identification | Phytochemistry. 2013 Nov;95:428-35.Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum.[Pubmed: 23906551 ]
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Hybridaphniphylline B Dilution Calculator
Hybridaphniphylline B Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 1.4668 mL | 7.3339 mL | 14.6677 mL | 29.3354 mL | 36.6693 mL |
| 5 mM | 0.2934 mL | 1.4668 mL | 2.9335 mL | 5.8671 mL | 7.3339 mL |
| 10 mM | 0.1467 mL | 0.7334 mL | 1.4668 mL | 2.9335 mL | 3.6669 mL |
| 50 mM | 0.0293 mL | 0.1467 mL | 0.2934 mL | 0.5867 mL | 0.7334 mL |
| 100 mM | 0.0147 mL | 0.0733 mL | 0.1467 mL | 0.2934 mL | 0.3667 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum.[Pubmed:23906551]
Phytochemistry. 2013 Nov;95:428-35.
Two Daphniphyllum alkaloid and iridoid hybrids with the hitherto unknown decacyclic fused skeletons, hybridaphniphyllines A and B, along with one diamino Daphniphyllum alkaloid, daphnicyclidin I, were isolated from dried stems and leaves of Daphniphyllum longeracemosum. Their structures were elucidated on the basis of extensive spectroscopic analysis, and the absolute configuration of daphnicyclidin I was deduced by the CD exciton chirality method. A biogenetic pathway for 1 and 2 involving natural Diels-Alder cycloaddition is proposed.
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