2-Methoxy-6-pentadecyl-1,4-benzoquinoneCAS# 144078-11-5 |
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| Cas No. | 144078-11-5 | SDF | Download SDF |
| PubChem ID | N/A | Appearance | Powder |
| Formula | C22H36O3 | M.Wt | 348.52 |
| Type of Compound | N/A | Storage | Desiccate at -20°C |
| Synonyms | 2-Methoxy-6-pentadecyl-2,5-cyclohexadiene-1,4-dione | ||
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
2-Methoxy-6-pentadecyl-1,4-benzoquinone Dilution Calculator
2-Methoxy-6-pentadecyl-1,4-benzoquinone Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 2.8693 mL | 14.3464 mL | 28.6928 mL | 57.3855 mL | 71.7319 mL |
| 5 mM | 0.5739 mL | 2.8693 mL | 5.7386 mL | 11.4771 mL | 14.3464 mL |
| 10 mM | 0.2869 mL | 1.4346 mL | 2.8693 mL | 5.7386 mL | 7.1732 mL |
| 50 mM | 0.0574 mL | 0.2869 mL | 0.5739 mL | 1.1477 mL | 1.4346 mL |
| 100 mM | 0.0287 mL | 0.1435 mL | 0.2869 mL | 0.5739 mL | 0.7173 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Microwave-mediated Claisen rearrangement followed by phenol oxidation: a simple route to naturally occurring 1,4-benzoquinones. The first syntheses of verapliquinones A and B and panicein A.[Pubmed:15903320]
J Org Chem. 2005 May 27;70(11):4414-22.
The naturally occurring 1,4-benzoquinones 2-methoxy-6-propyl-1,4-benzoquinone (1), 2-methoxy-6-pentyl-1,4-benzoquinone (primin 2), 2-Methoxy-6-pentadecyl-1,4-benzoquinone (3), 2-methoxy-6-heptadecyl-1,4-benzoquinone (dihydroirisquinone, pallasone B; 4) were synthesized by a simple protocol involving microwave accelerated Claisen rearrangement of allyl ethers 10, followed by hydrogenation of the side chain alkene, and oxidation to the quinone. The Claisen-based methodology was extended to the first synthesis of the marine benzoquinones verapliquinones A and B (5 and 6), and panicein A (7). Isoarnebifuranone (9) was also synthesized by a similar strategy.
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