Delgrandine

CAS# 145237-05-4

Delgrandine

Catalog No. BCN8122----Order now to get a substantial discount!

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Quality Control of Delgrandine

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Chemical structure

Delgrandine

3D structure

Chemical Properties of Delgrandine

Cas No. 145237-05-4 SDF Download SDF
PubChem ID 134715254 Appearance Powder
Formula C41H43NO12 M.Wt 741.77
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name [(1R,2R,3R,6R,7S,8S,9R,11R,13R,14R,17S,18S)-4,6,18-triacetyloxy-5-benzoyloxy-7-formyl-17-hydroxy-7,10-dimethyl-15-methylidene-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-13-yl] benzoate
SMILES CC(=O)OC1C2C(C3C4C56C1C3(CC2=C)C(C(C5C(C(C(C6OC(=O)C)OC(=O)C7=CC=CC=C7)OC(=O)C)(C)C=O)N4C)O)OC(=O)C8=CC=CC=C8
Standard InChIKey XDDAEJYWWRYPIF-PWXQXWHXSA-N
Standard InChI InChI=1S/C41H43NO12/c1-19-17-40-26-28(53-37(48)23-13-9-7-10-14-23)25(19)29(50-20(2)44)32(40)41-31(27(34(40)47)42(6)33(26)41)39(5,18-43)35(51-21(3)45)30(36(41)52-22(4)46)54-38(49)24-15-11-8-12-16-24/h7-16,18,25-36,47H,1,17H2,2-6H3/t25-,26?,27+,28-,29+,30?,31+,32+,33+,34+,35-,36?,39-,40-,41+/m0/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of Delgrandine

The herbs of Delphinium davidii

Protocol of Delgrandine

Structure Identification
Acta Chimica Sinica, 1992, 50(08):822-826.

The Alkaloidal Constituents of Delphinium grandiflorum L[J].[Reference: WebLink]


METHODS AND RESULTS:
The structures of Delgrandine (1) and acetylDelgrandine (2), isolated as minor constituents from the roots of Delphinium grandiflorum L., have been inferred from the spectroscopic analysis, especially the ~(13)C-~1H COSY, ~1H-~1H COSY and two dimensional NOE spectrum.
CONCLUSIONS:
1 and 2 are two rare examples among the C_(20) diterpenoid alkaloids reported so far in the sense that they are the most highly substituted with hydroxy or acetyloxy or benzoyloxy groups and characterized by having an aldehyde group at 4-c.

Delgrandine Dilution Calculator

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Delgrandine Molarity Calculator

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Preparing Stock Solutions of Delgrandine

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 1.3481 mL 6.7406 mL 13.4813 mL 26.9625 mL 33.7032 mL
5 mM 0.2696 mL 1.3481 mL 2.6963 mL 5.3925 mL 6.7406 mL
10 mM 0.1348 mL 0.6741 mL 1.3481 mL 2.6963 mL 3.3703 mL
50 mM 0.027 mL 0.1348 mL 0.2696 mL 0.5393 mL 0.6741 mL
100 mM 0.0135 mL 0.0674 mL 0.1348 mL 0.2696 mL 0.337 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on Delgrandine

The Alkaloidal Constituents of Delphinium grandiflorum L[J].

Acta Chimica Sinica, 1992, 50(08):822-826.

The structures of Delgrandine (1) and acetylDelgrandine (2), isolated as minor constituents from the roots of Delphinium grandiflorum L., have been inferred from the spectroscopic analysis, especially the ~(13)C-~1H COSY, ~1H-~1H COSY and two dimensional NOE spectrum. 1 and 2 are two rare examples among the C_(20) diterpenoid alkaloids reported so far in the sense that they are the most highly substituted with hydroxy or acetyloxy or benzoyloxy groups and characterized by having an aldehyde group at 4-c.

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