GamboginCAS# 173792-67-1 |
Quality Control & MSDS
Number of papers citing our products
Chemical structure
3D structure
| Cas No. | 173792-67-1 | SDF | Download SDF |
| PubChem ID | 102004809 | Appearance | Powder |
| Formula | C38H46O6 | M.Wt | 598.8 |
| Type of Compound | Miscellaneous | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| SMILES | CC(=CCCC1(C=CC2=C(O1)C(=C3C(=C2O)C(=O)C4=CC5CC6C4(O3)C(C5=O)(OC6(C)C)CC=C(C)C)CC=C(C)C)C)C | ||
| Standard InChIKey | UVSUFYGCWITFIZ-HHTAKYNCSA-N | ||
| Standard InChI | InChI=1S/C38H46O6/c1-21(2)11-10-16-36(9)17-15-25-30(39)29-31(40)27-19-24-20-28-35(7,8)44-37(34(24)41,18-14-23(5)6)38(27,28)43-33(29)26(32(25)42-36)13-12-22(3)4/h11-12,14-15,17,19,24,28,39H,10,13,16,18,20H2,1-9H3/t24-,28?,36-,37?,38-/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
| Description | 1. Gambogin is a cytotoxic xanthone. |
Gambogin Dilution Calculator
Gambogin Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 1.67 mL | 8.35 mL | 16.7001 mL | 33.4001 mL | 41.7502 mL |
| 5 mM | 0.334 mL | 1.67 mL | 3.34 mL | 6.68 mL | 8.35 mL |
| 10 mM | 0.167 mL | 0.835 mL | 1.67 mL | 3.34 mL | 4.175 mL |
| 50 mM | 0.0334 mL | 0.167 mL | 0.334 mL | 0.668 mL | 0.835 mL |
| 100 mM | 0.0167 mL | 0.0835 mL | 0.167 mL | 0.334 mL | 0.4175 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Unified synthesis of caged Garcinia natural products based on a site-selective Claisen/Diels-Alder/Claisen rearrangement.[Pubmed:15210986]
Proc Natl Acad Sci U S A. 2004 Aug 17;101(33):12030-5.
A unified synthetic strategy toward caged Garcinia natural products has been designed and implemented. Central to the strategy is a tandem Claisen/Diels-Alder/Claisen rearrangement of a suitably substituted xanthone precursor to form forbesione (1a). Serving as a template, forbesione is then used to deliver representative members of this family, including desoxygaudichaudione A (4), desoxymorellin (5), and Gambogin (10). Studies on the timing of this reaction cascade suggest that the C-ring Claisen/Diels-Alder rearrangement proceeds initially and is followed by the A-ring Claisen reaction. The electronic and steric effects that govern the outcome of this cascade are presented.
Cytotoxic xanthones from Garcinia hanburyi.[Pubmed:8835458]
Phytochemistry. 1996 Feb;41(3):815-20.
Eleven novel cytotoxic xanthones, Gambogin, morellin dimethyl acetal, isomoreollin B, moreollic acid, gambogenic acid, gambogenin, isogambogenin, desoxygambogenin, gambogenin dimethyl acetal, gambogellic acid and hanburin were isolated together with four known xanthones, gambogic acid, isomorellin, morellic acid and desoxymorellin, from the dry latex of Garcinia hanburyi. The structures were elucidated by a detailed spectroscopic analysis.
Origins of selectivity in pericyclic reaction cascades for the synthesis of gambogin and lateriflorone.[Pubmed:16805534]
Org Lett. 2006 Jul 6;8(14):2989-92.
[reaction: see text] Quantum mechanical calculations demonstrate that the second step of a Claisen-Diels-Alder reaction cascade controls regioselectivity that gives advanced intermediates for the synthesis of Gambogin and 1-O-methyllateriflorone.
