YuanamideCAS# 102421-42-1 |
Quality Control & MSDS
Number of papers citing our products
Chemical structure
3D structure
| Cas No. | 102421-42-1 | SDF | Download SDF |
| PubChem ID | 10362429.0 | Appearance | Powder |
| Formula | C22H23NO5 | M.Wt | 381.43 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | 2,3,9,10-tetramethoxy-13-methyl-5,6-dihydroisoquinolino[2,1-b]isoquinolin-8-one | ||
| SMILES | CC1=C2C3=CC(=C(C=C3CCN2C(=O)C4=C1C=CC(=C4OC)OC)OC)OC | ||
| Standard InChIKey | YCRTZNIBHAKZMT-UHFFFAOYSA-N | ||
| Standard InChI | InChI=1S/C22H23NO5/c1-12-14-6-7-16(25-2)21(28-5)19(14)22(24)23-9-8-13-10-17(26-3)18(27-4)11-15(13)20(12)23/h6-7,10-11H,8-9H2,1-5H3 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
Yuanamide Dilution Calculator
Yuanamide Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 2.6217 mL | 13.1086 mL | 26.2171 mL | 52.4343 mL | 65.5428 mL |
| 5 mM | 0.5243 mL | 2.6217 mL | 5.2434 mL | 10.4869 mL | 13.1086 mL |
| 10 mM | 0.2622 mL | 1.3109 mL | 2.6217 mL | 5.2434 mL | 6.5543 mL |
| 50 mM | 0.0524 mL | 0.2622 mL | 0.5243 mL | 1.0487 mL | 1.3109 mL |
| 100 mM | 0.0262 mL | 0.1311 mL | 0.2622 mL | 0.5243 mL | 0.6554 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Regiodivergent Synthesis of Methylene and Methyl Ring-Fused Isoquinolinones: Base-Promoted Isomerization of N-Allyl Amides.[Pubmed:35404617]
J Org Chem. 2022 May 6;87(9):5925-5937.
Methylene and methyl tricyclic isoquinolinones were selectively prepared using a palladium(II)-catalyzed aerobic aza-Wacker reaction, followed by a base- and temperature-controlled Heck reaction catalyzed by palladium(0). Exo- to endo-double-bond migration in isoquinolinones was achieved with 93-99% yields by treatment of the Heck products with Cs(2)CO(3) in dimethyl sulfoxide (DMSO) at 150 degrees C. A probable mechanism for Cs(2)CO(3)-promoted olefin isomerization was proposed and examined using D-isotope labeling experiments. Finally, Yuanamide, a 13-methyl-8-oxoprotoberberine alkaloid, was synthesized using the palladium-catalyzed aza-Wacker/Heck/migration sequence.
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