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2-Propylpyridine

CAS# 622-39-9

2-Propylpyridine

Catalog No. BCN9794----Order now to get a substantial discount!

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Chemical structure

2-Propylpyridine

3D structure

Chemical Properties of 2-Propylpyridine

Cas No. 622-39-9 SDF Download SDF
PubChem ID 69320 Appearance Oil
Formula C8H11N M.Wt 121.2
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 2-propylpyridine
SMILES CCCC1=CC=CC=N1
Standard InChIKey OIALIKXMLIAOSN-UHFFFAOYSA-N
Standard InChI InChI=1S/C8H11N/c1-2-5-8-6-3-4-7-9-8/h3-4,6-7H,2,5H2,1H3
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Biological Activity of 2-Propylpyridine

Description2-Propylpyridine consistently imparts more translational energy in collisions than does 2-ethylpyridine and has larger energy transfer rates. Of the alkylated donors, 2-methylpyridine and 2-propylpyridine have larger probabilities for strong collisional energy transfer than does 2-ethylpyridine.

2-Propylpyridine Dilution Calculator

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2-Propylpyridine Molarity Calculator

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Preparing Stock Solutions of 2-Propylpyridine

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 8.2508 mL 41.2541 mL 82.5083 mL 165.0165 mL 206.2706 mL
5 mM 1.6502 mL 8.2508 mL 16.5017 mL 33.0033 mL 41.2541 mL
10 mM 0.8251 mL 4.1254 mL 8.2508 mL 16.5017 mL 20.6271 mL
50 mM 0.165 mL 0.8251 mL 1.6502 mL 3.3003 mL 4.1254 mL
100 mM 0.0825 mL 0.4125 mL 0.8251 mL 1.6502 mL 2.0627 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 2-Propylpyridine

Model studies on the pattern of volatiles generated in mixtures of amino acids, lipid-oxidation-derived aldehydes, and glucose.[Pubmed:21265545]

J Agric Food Chem. 2011 Feb 23;59(4):1449-56.

The development of flavor and browning in thermally treated foods results mainly from the Maillard reaction and lipid degradation but also from the interactions between both reaction pathways. To study these interactions, we analyzed the volatile compounds resulting from model reactions of lysine or glycine with aldehydes originating from lipid oxidation [hexanal, (E)-2-hexenal, or (2E,4E)-decadienal] in the presence and absence of glucose. The main reaction products identified in these model mixtures were carbonyl compounds, resulting essentially from amino-acid-catalyzed aldol condensation reactions. Several 2-alkylfurans were detected as well. Only a few azaheterocyclic compounds were identified, in particular 5-butyl-2-Propylpyridine from (E)-2-hexenal model systems and 2-pentylpyridine from (2E,4E)-decadienal model reactions. Although few reaction products were found resulting from the condensation of an amino acid with a lipid-derived aldehyde, the amino acid plays an important role in catalyzing the degradation and further reaction of these carbonyl compounds. These results suggest that amino-acid-induced degradations and further reactions of lipid oxidation products may be of considerable importance in thermally processed foods.

Alkylation effects on strong collisions of highly vibrationally excited alkylated pyridines with CO2.[Pubmed:17388383]

J Phys Chem A. 2007 May 17;111(19):4073-80.

The role of alkylation on the energy partitioning in strong collisions with CO2 was investigated for highly vibrationally excited 2-ethylpyridine (2EP) and 2-Propylpyridine (2PP) prepared with E(vib) approximately 38,570 and 38,870 cm(-1), respectively, using lambda = 266 nm light. Nascent energy gain in CO2 (00(0)0) rotation and translation was measured with high-resolution transient absorption spectroscopy at lambda approximately 4.3 microm and the results are compared to earlier relaxation studies of pyridine (E(vib) = 37,950 cm(-1)) and 2-methylpyridine (2MP, Evib = 38,330 cm(-1)). Overall, the alkylated donors impart less rotational and translational energy to CO2 than does pyridine. 2PP consistently imparts more translational energy in collisions than does 2EP and has larger energy transfer rates. Of the alkylated donors, 2MP and 2PP have larger probabilities for strong collisional energy transfer than does 2EP. Two competing processes are discussed: donors with longer alkyl chains have lower average energy per mode and fewer strong collisions but longer alkyl chains increase donor flexibility, leading to higher state densities that enhance energy loss via strong collisions. A comparison of state density effects based on Fermi's Golden Rule shows that 2PP has more strong collisions than predicted while 2EP has fewer. The role of torsional motion in the hot donors is considered. Comparison of effective impact parameters shows that the alkylated donors undergo strong collisions with CO2 via a less repulsive part of the intermolecular potential than does pyridine.

pH of solution greatly affects sorption of ionizable compounds into low-density polyethylene film.[Pubmed:15853392]

J Agric Food Chem. 2005 May 4;53(9):3488-92.

Sorption of ionizable compounds of pyridines and aromatic carboxylic acids into low-density polyethylene (LDPE) film was investigated as a function of pH ranging from 4 to 7. The sorptions for pyridines were increased with increasing pH. Within the range examined, pH 7 was observed to promote the highest degree of sorption. When the pH increased by one unit from 6 to 7, the sorptions for 2-Propylpyridine and 2,4,6-trimethylpyridine were both increased approximately 3.8 and 10.5 times, respectively. At pH 4, the sorption for the pyridines entirely disappeared. In contrast, the sorptions for aromatic carboxylic acids increased with decreasing pH. Within the range examined, pH 4 was observed to promote the highest degree of sorption. The magnitude of sorption for pyridines and carboxylic acids apparently depended on the affinity (delta(c)) of these compounds for LDPE film. Another factor affecting the sorption at various pHs was the pK(a) of these compounds; the sorption greatly decreased with the ionization degree of these compounds. To elucidate the phenomena, the following thermodynamic sorption equation was applied: S = S(0)gamma exp[V(v){(delta(w) - delta(v))(2) - delta(c)(2))/RT}. The plots of ln S for pyridines vs the term of the equation gave an insufficient relationship (r = 0.519). In contrast, taking into account the ratio (chi(i)()) of concentration of un-ionized compound to total concentration, the improvement for the equation was made: S' = S/chi(i)() = S(0)gamma exp[V(v){(delta(w) - delta(v))(2) - delta(c)(2))/RT}. The plots of ln S' vs the term of the equation gave a better relationship (r = 0.884). Furthermore, the equation was also applicable for the sorption behavior of carboxylic acids into LDPE (r = 0.769).

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