AmabilineCAS# 17958-43-9 |
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| Cas No. | 17958-43-9 | SDF | Download SDF |
| PubChem ID | 442706 | Appearance | Powder |
| Formula | C15H25NO4 | M.Wt | 283.37 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | [(8S)-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl]methyl (2S)-2-hydroxy-2-[(1S)-1-hydroxyethyl]-3-methylbutanoate | ||
| SMILES | CC(C)C(C(C)O)(C(=O)OCC1=CCN2C1CCC2)O | ||
| Standard InChIKey | DRVWTOSBCBKXOR-WHOFXGATSA-N | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
The herbs of Cynoglossum amabile
| Structure Identification | Org Lett. 2012 Apr 6;14(7):1869-71.Enantioselective total synthesis of (+)-amabiline.[Pubmed: 22432912 ]
Org Lett. 2009 Jul 16;11(14):3160-2.A chemoenzymatic total synthesis of (+)-amabiline.[Pubmed: 19586069]
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Amabiline Dilution Calculator
Amabiline Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 3.529 mL | 17.6448 mL | 35.2896 mL | 70.5791 mL | 88.2239 mL |
| 5 mM | 0.7058 mL | 3.529 mL | 7.0579 mL | 14.1158 mL | 17.6448 mL |
| 10 mM | 0.3529 mL | 1.7645 mL | 3.529 mL | 7.0579 mL | 8.8224 mL |
| 50 mM | 0.0706 mL | 0.3529 mL | 0.7058 mL | 1.4116 mL | 1.7645 mL |
| 100 mM | 0.0353 mL | 0.1764 mL | 0.3529 mL | 0.7058 mL | 0.8822 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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A chemoenzymatic total synthesis of (+)-amabiline.[Pubmed:19586069]
Org Lett. 2009 Jul 16;11(14):3160-2.
The readily available and enzymatically derived cis-1,2-dihydrocatechol 3 has been converted, over 15 steps, into (+)-Amabiline, the non-natural enantiomeric form of a crinine-type alkaloid.
Enantioselective total synthesis of (+)-amabiline.[Pubmed:22432912]
Org Lett. 2012 Apr 6;14(7):1869-71.
The first total synthesis of (+)-Amabiline, an unsaturated pyrrolizidine alkaloid from Cynoglossum amabile, is reported. This convergent, enantioselective synthesis proceeds in 15 steps (10-step longest linear sequence) in 6.2% overall yield and features novel methodology to construct the unsaturated pyrrolizidine or (-)-supinidine core.
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