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Foresaconitine

CAS# 73870-35-6

Foresaconitine

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Chemical structure

Foresaconitine

3D structure

Chemical Properties of Foresaconitine

Cas No. 73870-35-6 SDF Download SDF
PubChem ID 132471340 Appearance Powder
Formula C35H49NO9 M.Wt 627.8
Type of Compound Alkaloids Storage Desiccate at -20°C
Synonyms Vilmorrianine C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
SMILES CCN1CC2(CCC(C34C2C(C(C31)C5(CC(C6CC4C5C6OC(=O)C7=CC=C(C=C7)OC)OC)OC(=O)C)OC)OC)COC
Standard InChIKey LYUPEIXJYAJCHL-VMQSQICBSA-N
Standard InChI InChI=1S/C35H49NO9/c1-8-36-17-33(18-39-3)14-13-25(42-6)35-23-15-22-24(41-5)16-34(45-19(2)37,27(31(35)36)29(43-7)30(33)35)26(23)28(22)44-32(38)20-9-11-21(40-4)12-10-20/h9-12,22-31H,8,13-18H2,1-7H3/t22-,23-,24+,25?,26-,27?,28+,29?,30-,31?,33+,34-,35?/m1/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of Foresaconitine

The roots of Aconitum kusnenzoffii Reichb.

Protocol of Foresaconitine

Structure Identification
Zhong Yao Cai. 2013 Jun;36(6):938-40.

Chemical constituents of Aconitum bulleyanum.[Pubmed: 24380280]

To study the chemical constituents of chloroform fraction from Aconitum bulleyanum.
METHODS AND RESULTS:
The compounds were isolated by various chromatographic techniques and identified by spectroscopic methods. RESULTS: 7 compounds were obtained and identified as yunaconitine (1), crassicaudine (2), Foresaconitine (3), chasmaconitine (4), bulleyaconitine A (5), franchetine (6), and beta-sitosterol (7),
CONCLUSIONS:
Compounds 2-7 are isolated from this plant for the first time.

Foresaconitine Dilution Calculator

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Foresaconitine Molarity Calculator

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Preparing Stock Solutions of Foresaconitine

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 1.5929 mL 7.9643 mL 15.9286 mL 31.8573 mL 39.8216 mL
5 mM 0.3186 mL 1.5929 mL 3.1857 mL 6.3715 mL 7.9643 mL
10 mM 0.1593 mL 0.7964 mL 1.5929 mL 3.1857 mL 3.9822 mL
50 mM 0.0319 mL 0.1593 mL 0.3186 mL 0.6371 mL 0.7964 mL
100 mM 0.0159 mL 0.0796 mL 0.1593 mL 0.3186 mL 0.3982 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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Background on Foresaconitine

Foresaconitine(Vilmorrianine C) is a norditerpenoid alkaloid isolated from the processed tubers of Aconitum carmichaeli.

References:
[1]. Shim SH, et al. Norditerpenoid alkaloids from the processed tubers of Aconitum carmichaeli. Chem Pharm Bull (Tokyo). 2003 Aug;51(8):999-1002. [2]. ZhaohongWang, et al. Simultaneous determination of three aconitum alkaloids in urine by LC-MS-MS. J Pharm Biomed Anal. 2007 Sep 21;45(1):145-8.

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References on Foresaconitine

[Chemical constituents of Aconitum bulleyanum].[Pubmed:24380280]

Zhong Yao Cai. 2013 Jun;36(6):938-40.

OBJECTIVE: To study the chemical constituents of chloroform fraction from Aconitum bulleyanum. METHODS: The compounds were isolated by various chromatographic techniques and identified by spectroscopic methods. RESULTS: 7 compounds were obtained and identified as yunaconitine (1), crassicaudine (2), Foresaconitine (3), chasmaconitine (4), bulleyaconitine A (5), franchetine (6), and beta-sitosterol (7), CONCLUSION: Compounds 2-7 are isolated from this plant for the first time.

Simultaneous determination of three aconitum alkaloids in urine by LC-MS-MS.[Pubmed:17555909]

J Pharm Biomed Anal. 2007 Sep 21;45(1):145-8.

A sensitive method has been developed for the identification and quantification of the toxic alkaloids yunaconitine, crassicauline A, and Foresaconitine in urine specimens. After solid-phase extraction using Oasis MCX cartridges, the extracts were analyzed by LC-MS-MS. The limit of detection is 0.03 ng/mL urine for yunaconitine and 0.05 ng/mL urine for crassicauline A and Foresaconitine; the limit of quantitation is 0.15 ng/mL urine for yunaconitine and 0.20 ng/mL urine for crassicauline A and Foresaconitine. The method was employed in the analysis of the urine of a 55-year-old male who died after ingestion of herbal medicine powder made from the roots of aconite. Yunaconitine, crassicauline A and Foresaconitine were identified in the urine. Crassicauline A and Foresaconitine were thus identified in a biological specimen for the first time.

Norditerpenoid alkaloids from the processed tubers of Aconitum carmichaeli.[Pubmed:12913245]

Chem Pharm Bull (Tokyo). 2003 Aug;51(8):999-1002.

Four new and five known norditerpenoid alkaloids were isolated from the processed tubers of Aconitum carmichaeli. The new alkaloids are 14-O-cinnamoylneoline (3), 14-O-anisoylneoline (4) 14-O-veratroylneoline (5), and lipo-14-O-anisoylbikhaconine (8). The known alkaloids are neoline (1), 14-O-acetylneoline (2), Foresaconitine (6), crassicauline A (7), and lipohypaconitine (9). Alkaloids 2, 6, and 7 were isolated from this plant for the first time. The structures of the new alkaloids were established by spectroscopic and chemical methods.

Description

Foresaconitine(Vilmorrianine C) is a norditerpenoid alkaloid isolated from the processed tubers of Aconitum carmichaeli.

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