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4-Benzyloxyindole

CAS# 20289-26-3

4-Benzyloxyindole

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Quality Control of 4-Benzyloxyindole

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Chemical structure

4-Benzyloxyindole

3D structure

Chemical Properties of 4-Benzyloxyindole

Cas No. 20289-26-3 SDF Download SDF
PubChem ID 88465 Appearance Powder
Formula C15H13NO M.Wt 223.3
Type of Compound N/A Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 4-phenylmethoxy-1H-indole
SMILES C1=CC=C(C=C1)COC2=CC=CC3=C2C=CN3
Standard InChIKey LJFVSIDBFJPKLD-UHFFFAOYSA-N
Standard InChI InChI=1S/C15H13NO/c1-2-5-12(6-3-1)11-17-15-8-4-7-14-13(15)9-10-16-14/h1-10,16H,11H2
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

4-Benzyloxyindole Dilution Calculator

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4-Benzyloxyindole Molarity Calculator

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Preparing Stock Solutions of 4-Benzyloxyindole

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 4.4783 mL 22.3914 mL 44.7828 mL 89.5656 mL 111.957 mL
5 mM 0.8957 mL 4.4783 mL 8.9566 mL 17.9131 mL 22.3914 mL
10 mM 0.4478 mL 2.2391 mL 4.4783 mL 8.9566 mL 11.1957 mL
50 mM 0.0896 mL 0.4478 mL 0.8957 mL 1.7913 mL 2.2391 mL
100 mM 0.0448 mL 0.2239 mL 0.4478 mL 0.8957 mL 1.1196 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 4-Benzyloxyindole

Synthetic studies of psilocin analogs having either a formyl group or bromine atom at the 5- or 7-position.[Pubmed:11824592]

Chem Pharm Bull (Tokyo). 2002 Jan;50(1):92-9.

Psilocin analogs having either a formyl group (9-12) or a bromine atom (13-18) at the 5- or 7-position have been prepared for the first time. Syntheses of 5- and 7-bromo derivatives of 4-hydroxy- (23, 24, 28) and 4-Benzyloxyindole-3-carbaldehyde (19, 25, 29, 30), 4-Benzyloxyindole-3-acetonitriles (20, 31), and 4-benzyloxy-N,N-dimethyltryptamine (32, 34, 35) have also been established.

Synthesis, pharmacology, and molecular modeling of novel 4-alkyloxy indole derivatives related to cannabimimetic aminoalkyl indoles (AAIs).[Pubmed:9313864]

Bioorg Med Chem. 1997 Aug;5(8):1591-600.

Several novel 4-alkyloxy-aminoalkyl indole derivatives 3 were synthesized from 4-Benzyloxyindole (1). Alkylation of 1 with 4-(2-chloroethyl)morpholine (NaH/HMPA) formed 2. Deprotection using palladium hydroxide on carbon/hydrogen followed by alkylation with the appropriate alkyl bromide gave the target compounds 3b-3j. In the synthesis of 3i and 3j, the appropriate alkyl bromides 13 and 17 were prepared from the commercially available 1-naphthylethyl bromide 9 using the chain lengthening sequences as shown in Scheme 3. In receptor binding assay and in vivo testing, the long chain alkoxy compounds 3g and 3h (Ki = 127 nM) showed affinity for the CB1 receptor which was approximately 16-35-fold less than that of WIN 55,225. However, the pharmacological profile of 3h mimics that of WIN 55,212. An examination of the SAR of these analogues shows that translocating the napthyl group in AAIs from the C-3 position to C-4 via an oxygen (ether linkage) decreases activity which is in contrast to previous findings that a naphthylcarbonyl at C-4 retains activity. The present work points to the importance of the role of a keto group in the interaction with the receptor. Molecular modeling work suggests that, although reasonable superposition of key structural features between delta 9-THC and AAIs can be made, the overlay is not straightforward. The present study also illustrates the difficulty in accommodating AAIs into the cannabinoid pharmacophore and it seems likely that a unique pharmacophore will need to be developed. Only then will the similarities to and differences from the classical cannabinoid pharmacophore be clearly delineated.

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