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5,7,8-Trimethoxycoumarin

CAS# 60796-65-8

5,7,8-Trimethoxycoumarin

2D Structure

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5,7,8-Trimethoxycoumarin: 5mg $265 In Stock
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Quality Control of 5,7,8-Trimethoxycoumarin

3D structure

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5,7,8-Trimethoxycoumarin

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Chemical Properties of 5,7,8-Trimethoxycoumarin

Cas No. 60796-65-8 SDF Download SDF
PubChem ID 6482974 Appearance Cryst.
Formula C12H12O5 M.Wt 236.2
Type of Compound Coumarins Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 5,7,8-trimethoxychromen-2-one
SMILES COC1=CC(=C(C2=C1C=CC(=O)O2)OC)OC
Standard InChIKey MSFXSDYNQKVMTJ-UHFFFAOYSA-N
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of 5,7,8-Trimethoxycoumarin

The herbs of Viola yedonensis Makino

Biological Activity of 5,7,8-Trimethoxycoumarin

DescriptionStandard reference

Protocol of 5,7,8-Trimethoxycoumarin

Structure Identification
Phytochemistry.1990,29(5):1704–1706.

Monoterpenoid phloroacetophenones from Euodia latifolia.[Reference: WebLink]


METHODS AND RESULTS:
Extracts of Euodia latifolia provided mainly coumarin derivatives, 5,7,8-Trimethoxycoumarin, bergapten, and 6,7,8-trimethoxycoumarin, and minor amounts of two new natural products which have the tetracyclic monoterpenoid phloroacetophenone skeleton.
CONCLUSIONS:
X-Ray structure determination showed that one of the new products is desbenzylidenerubramin. The spectral data established that the other is an isomer of desbenzylidenerubramin.

5,7,8-Trimethoxycoumarin Dilution Calculator

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Preparing Stock Solutions of 5,7,8-Trimethoxycoumarin

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 4.2337 mL 21.1685 mL 42.337 mL 84.674 mL 105.8425 mL
5 mM 0.8467 mL 4.2337 mL 8.4674 mL 16.9348 mL 21.1685 mL
10 mM 0.4234 mL 2.1169 mL 4.2337 mL 8.4674 mL 10.5843 mL
50 mM 0.0847 mL 0.4234 mL 0.8467 mL 1.6935 mL 2.1169 mL
100 mM 0.0423 mL 0.2117 mL 0.4234 mL 0.8467 mL 1.0584 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 5,7,8-Trimethoxycoumarin

Nonvolatiles of commercial lime and grapefruit oils separated by high-speed countercurrent chromatography.[Pubmed:16536603]

J Agric Food Chem. 2006 Mar 22;54(6):2242-52.

The nonvolatile fractions of cold-pressed peel oils of Key and Persian lime as well as grapefruit were separated by high-speed countercurrent chromatography (HS-CCC). In addition to the isolation of the main coumarins, psoralens and polymethoxyflavones, a number of minor constituents were enriched and successfully characterized by GC-MS and HPLC-UV. 5,7,8-Trimethoxycoumarin and the cyclical acetals of oxypeucedanin hydrate with citral were determined as new nonvolatile trace constituents of lime oils and confirmed by NMR spectroscopy. The citral oxypeucedaninyl acetals were found particularly in Key lime oil type A, which as a result of the juice-oil contact, is exposed to acidic conditions during industrial processing. Some of the confirmed minor constituents, such as pabulenol, isooxypeucedanin, and oxypeucedanin methanolate in lime as well as auraptenol in grapefruit, may have been generated by hydrolysis-sensitive precursors during CCC separation or their respective industrial processing techniques.

[Studies on the chemical constituents of Rutaceae++ plants. LXVI. The chemical constituents of Toddalia asiatica (L.) Lam. (T. aculeata Pers.). (1). Chemical constituents of the root bark].[Pubmed:1783985]

Yakugaku Zasshi. 1991 Jul;111(7):365-75.

Chemical constituents of the root bark of Toddalia asiatica (L.) Lam. (T. aculeata Pers.), Rutaceae, were examined. In addition to twelve known coumarins [toddaculin (2), coumurrayin (5), toddanone (6), 8-(3,3-dimethylallyl)-6,7-dimethoxycoumarin (7), isopimpinellin (8), 6-(3-chloro-2-hydroxy-3-methylbutyl)-5,7-dimethoxycoumarin (9), 6-formyllimettin (10), 5,7,8-Trimethoxycoumarin (12), toddasin (13), (+)-toddanol (14), 6-(2-hydroxy-3-methoxy-3-methylbutyl)-5,7-dimethoxycoumarin (18), and toddalolactone (21)] five new coumarins [toddalenol (17), toddalosin (19), 5-methoxysuberenon (23), toddalenone (24), and 8-formyllimettin (25)] were isolated. Furthermore seven known benzo[c]phenanthridine alkaloids [des-N-methylchelerythrine (4), oxychelerythrine (15), arnottianamide (16), oxyavicine (22), avicine (30), chelerythrine (31), and chelerythrine-psi-cyanide (34)] and four known quinoline alkaloids [N-methylflindersine (11), 4-methoxy-1-methyl-2-quinolone (20), skimmianine (35), integriquinolone (36)], one known triterpenoid [beta-amyrin (3)], and four unknown components [unknown I-IV (26)-(29)] were isolated.

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