H- ß-HoGlu-OH.HClCAS# 58610-41-6 |
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| Cas No. | 58610-41-6 | SDF | Download SDF |
| PubChem ID | 2761505 | Appearance | Powder |
| Formula | C6H12ClNO4 | M.Wt | 197.6 |
| Type of Compound | N/A | Storage | Desiccate at -20°C |
| Synonyms | 58610-41-6; L-beta-Homoalanine hydrochloride; (s)-3-aminobutanoic acid hydrochloride | ||
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | (3S)-3-aminobutanoic acid;hydrochloride | ||
| SMILES | CC(CC(=O)O)N.Cl | ||
| Standard InChIKey | UHYVVUABAWKTJJ-DFWYDOINSA-N | ||
| Standard InChI | InChI=1S/C4H9NO2.ClH/c1-3(5)2-4(6)7;/h3H,2,5H2,1H3,(H,6,7);1H/t3-;/m0./s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
H- ß-HoGlu-OH.HCl Dilution Calculator
H- ß-HoGlu-OH.HCl Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 5.0607 mL | 25.3036 mL | 50.6073 mL | 101.2146 mL | 126.5182 mL |
| 5 mM | 1.0121 mL | 5.0607 mL | 10.1215 mL | 20.2429 mL | 25.3036 mL |
| 10 mM | 0.5061 mL | 2.5304 mL | 5.0607 mL | 10.1215 mL | 12.6518 mL |
| 50 mM | 0.1012 mL | 0.5061 mL | 1.0121 mL | 2.0243 mL | 2.5304 mL |
| 100 mM | 0.0506 mL | 0.253 mL | 0.5061 mL | 1.0121 mL | 1.2652 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Nitroarenes as the Nitrogen Source in Intermolecular Palladium-Catalyzed Aryl C-H Bond Aminocarbonylation Reactions.[Pubmed:28370898]
Angew Chem Int Ed Engl. 2017 Apr 10;56(16):4530-4534.
A three-component palladium-catalyzed aminocarbonylation of aryl and heteroaryl sp(2) C-H bonds using nitroarenes as the nitrogen source was achieved using Mo(CO)6 as the reductant and origin of the CO. This intermolecular C-H bond functionalization does not requires any exogenous ligand to be added, and our mechanism experiments indicate that the palladacycle catalyst serves two roles in the aminocarbonylation reaction: reduce the nitroarene to a nitrosoarene and activate the sp(2) C-H bond.
An Annulative Synthetic Strategy for Building Triphenylene Frameworks by Multiple C-H Bond Activations.[Pubmed:28371060]
Angew Chem Int Ed Engl. 2017 Apr 24;56(18):5007-5011.
C-H activation is a versatile tool for appending aryl groups to aromatic systems. However, heavy demands on multiple catalytic cycle operations and site-selectivity have limited its use for graphene segment synthesis. A Pd-catal- yzed one-step synthesis of functionalized triphenylene frameworks is disclosed, which proceeds by 2- or 4-fold C-H arylation of unactivated benzene derivatives. A Pd2 (dibenzylideneacetone)3 catalytic system, using cyclic diaryliodonium salts as pi-extending agents, leads to site-selective inter- and intramolecular tandem arylation sequences. Moreover, N-substituted triphenylenes are applied to a field-effect transistor sensor for rapid, sensitive, and reversible alcohol vapor detection.
Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp(2) C-H Bond Functionalization Reaction.[Pubmed:28370972]
Angew Chem Int Ed Engl. 2017 Apr 24;56(18):5091-5095.
A hydroxy group chelation-assisted stereospecific oxidative cross-coupling reaction between alkenes was developed under mild reaction conditions. In the presence of palladium catalyst, the alkenes tethered with hydroxy functionality can couple efficiently with electron-deficient alkenes to form the corresponding multi-substituted olefin products. The hydroxy group on the substrate could play dual roles in reaction, acting as the directing group for alkenyl C-H bond activation and controlling the stereoselectivity of the products.
Ligand-Promoted meta-C-H Functionalization of Benzylamines.[Pubmed:28371173]
Angew Chem Int Ed Engl. 2017 Apr 24;56(18):5125-5129.
Meta-C-H functionalization of benzylamines has been developed using a Pd(II) /transient mediator strategy. Using 2-pyridone ligands and 2-carbomethoxynorbornene (NBE-CO2 Me) as the mediator, arylation, amination, and chlorination of benzylamines are realized. This protocol features a broad substrate scope and is compatible with heterocylic coupling partners. Moreover, the loading of the Pd can be lowered to 2.5 mol % by using the optimal ligand.
