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Heliocurassavinine

CAS# 82374-02-5

Heliocurassavinine

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Chemical structure

Heliocurassavinine

3D structure

Chemical Properties of Heliocurassavinine

Cas No. 82374-02-5 SDF Download SDF
PubChem ID 158085 Appearance Gum
Formula C15H27NO4 M.Wt 285.38
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name [(1S,8R)-2,3,5,6,7,8-hexahydro-1H-pyrrolizin-1-yl]methyl (2R)-2-hydroxy-2-[(1S)-1-hydroxyethyl]-3-methylbutanoate
SMILES CC(C)C(C(C)O)(C(=O)OCC1CCN2C1CCC2)O
Standard InChIKey BWQSLRZZOVFVHJ-KYEXWDHISA-N
Standard InChI InChI=1S/C15H27NO4/c1-10(2)15(19,11(3)17)14(18)20-9-12-6-8-16-7-4-5-13(12)16/h10-13,17,19H,4-9H2,1-3H3/t11-,12+,13+,15+/m0/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Protocol of Heliocurassavinine

Structure Identification
Phytochemistry,1982,21(7): 1775-1779.

Minor alkaloids of Heliotropium curassavicum[Reference: WebLink]

Isolation and structure determination of the minor alkaloids of Heliotropium curassavicum are described.
METHODS AND RESULTS:
These include the new pyrrolizidine alkaloids, heliocurassavine [isoretronecanol (−) curassavine], heliocoromandaline [isoretronecanol (+) viridiflorate], heliocurassavicine [isoretronecanol (−) trachelanthate], Heliocurassavinine [laburnine (−) trachelanthate], curassavinine [supinidine (−) curassavate], coromandalinine [supinidine (+) viridifloratel, heliovinine [supinidine (−) trachelanthate] and curassanecine [1-(α-hydroxy-methyl)-8α pyrrolizidin-1β-ol].
CONCLUSIONS:
Structures were established by high resolution 1H NMR, mass spectrometry and paper electrophoresis of the alkaloids and their hydrolysis products.

Heliocurassavinine Dilution Calculator

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Heliocurassavinine Molarity Calculator

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Preparing Stock Solutions of Heliocurassavinine

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.5041 mL 17.5205 mL 35.041 mL 70.082 mL 87.6025 mL
5 mM 0.7008 mL 3.5041 mL 7.0082 mL 14.0164 mL 17.5205 mL
10 mM 0.3504 mL 1.752 mL 3.5041 mL 7.0082 mL 8.7602 mL
50 mM 0.0701 mL 0.3504 mL 0.7008 mL 1.4016 mL 1.752 mL
100 mM 0.035 mL 0.1752 mL 0.3504 mL 0.7008 mL 0.876 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on Heliocurassavinine

Minor alkaloids of Heliotropium curassavicum

Phytochemistry Volume 21, Issue 7, 1982, Pages 1775-1779

Isolation and structure determination of the minor alkaloids of Heliotropium curassavicum are described. These include the new pyrrolizidine alkaloids, heliocurassavine [isoretronecanol (−) curassavine], heliocoromandaline [isoretronecanol (+) viridiflorate], heliocurassavicine [isoretronecanol (−) trachelanthate], Heliocurassavinine [laburnine (−) trachelanthate], curassavinine [supinidine (−) curassavate], coromandalinine [supinidine (+) viridifloratel, heliovinine [supinidine (−) trachelanthate] and curassanecine [1-(α-hydroxy-methyl)-8α pyrrolizidin-1β-ol]. Structures were established by high resolution 1H NMR, mass spectrometry and paper electrophoresis of the alkaloids and their hydrolysis products.

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