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(+)-δ-Tocopherol

CAS# 119-13-1

(+)-δ-Tocopherol

2D Structure

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Quality Control of (+)-δ-Tocopherol

Quality Control & MSDS

3D structure

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(+)-δ-Tocopherol

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Chemical Properties of (+)-δ-Tocopherol

Cas No. 119-13-1 SDF Download SDF
PubChem ID 92094 Appearance Oil
Formula C27H46O2 M.Wt 402.7
Type of Compound Phenols Storage Desiccate at -20°C
Synonyms Delta-Tocopherol; 8-Methyltocol; (+)-Delta-Tocopherol; D-Delta-TOCOPHEROL
Solubility DMSO : 125 mg/mL (310.44 mM; Need ultrasonic)
Chemical Name (2R)-2,8-dimethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-3,4-dihydrochromen-6-ol
SMILES CC1=CC(=CC2=C1OC(CC2)(C)CCCC(C)CCCC(C)CCCC(C)C)O
Standard InChIKey GZIFEOYASATJEH-VHFRWLAGSA-N
Standard InChI InChI=1S/C27H46O2/c1-20(2)10-7-11-21(3)12-8-13-22(4)14-9-16-27(6)17-15-24-19-25(28)18-23(5)26(24)29-27/h18-22,28H,7-17H2,1-6H3/t21-,22-,27-/m1/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of (+)-δ-Tocopherol

The roots of Stemona sessilifolia

Biological Activity of (+)-δ-Tocopherol

Description(+)-Delta-Tocopherol has antioxidant activity.

Protocol of (+)-δ-Tocopherol

Structure Identification
J Agric Food Chem. 2002 Mar 27;50(7):1815-21.

Development and validation of oxygen radical absorbance capacity assay for lipophilic antioxidants using randomly methylated beta-cyclodextrin as the solubility enhancer.[Pubmed: 11902917 ]

We recently reported the improved oxygen radical absorbance capacity (ORAC) assay using fluorescein (FL) as the fluorescent probe. The current ORAC(FL) assay is limited in hydrophilic antioxidant due to the aqueous environment of the assay. Lipophilic antioxidants mainly include the vitamin E family and carotenoids, which play a critical role in biological defense systems.
METHODS AND RESULTS:
In this paper, we expanded the current ORAC(FL) assay to lipophilic antioxidants. Randomly methylated beta-cyclodextrin (RMCD) was introduced as the water solubility enhancer for lipophilic antioxidants. Seven percent RMCD (w/v) in a 50% acetone-H(2)O mixture was found to sufficiently solubilize vitamin E compounds and other lipophilic phenolic antioxidants in 75 mM phosphate buffer (pH 7.4). This newly developed ORAC assay (abbbreviated ORAC(FL-LIPO)) was validated through linearity, precision, accuracy, and ruggedness. The validation results demonstrate that the ORAC(FL-LIPO) assay is reliable and robust. For the first time, by using 6-hydroxy-2,5,7,8-tetramethyl-2-carboxylic acid as a standard (1.0), the ORAC values of alpha-tocopherol, (+)-gamma-tocopherol, (+)-Delta-Tocopherol((+)-δ-Tocopherol), alpha-tocopherol acetate, tocotrienols, 2,6-di-tert-butyl-4-methylphenol, and gamma-oryzanol were determined to be 0.5 +/- 0.02, 0.74 +/- 0.03, 1.36 +/- 0.14, 0.00, 0.91 +/- 0.04, 0.16 +/- 0.01, and 3.00 +/- 0.26, respectively.
CONCLUSIONS:
The structural information of oxidized alpha-tocopherol obtained by liquid chromatography/mass spectrometry reveals that the mechanism for the reaction between the vitamin E and the peroxyl radical follows the hydrogen atom transfer mechanism, which is in agreement with the notion that vitamin E is the chain-breaking antioxidant.

(+)-δ-Tocopherol Dilution Calculator

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(+)-δ-Tocopherol Molarity Calculator

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Preparing Stock Solutions of (+)-δ-Tocopherol

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.4832 mL 12.4162 mL 24.8324 mL 49.6648 mL 62.081 mL
5 mM 0.4966 mL 2.4832 mL 4.9665 mL 9.933 mL 12.4162 mL
10 mM 0.2483 mL 1.2416 mL 2.4832 mL 4.9665 mL 6.2081 mL
50 mM 0.0497 mL 0.2483 mL 0.4966 mL 0.9933 mL 1.2416 mL
100 mM 0.0248 mL 0.1242 mL 0.2483 mL 0.4966 mL 0.6208 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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Description

Delta-Tocopherol is an isomer of Vitamin E.

Keywords:

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