(1S,2R)-1-Amino-2-indanolCAS# 126456-43-7 |
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Quality Control & MSDS
3D structure
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| Cas No. | 126456-43-7 | SDF | Download SDF |
| PubChem ID | 9866743 | Appearance | Powder |
| Formula | C9H11NO | M.Wt | 149 |
| Type of Compound | N/A | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | (1S,2R)-1-amino-2,3-dihydro-1H-inden-2-ol | ||
| SMILES | C1C(C(C2=CC=CC=C21)N)O | ||
| Standard InChIKey | LOPKSXMQWBYUOI-BDAKNGLRSA-N | ||
| Standard InChI | InChI=1S/C9H11NO/c10-9-7-4-2-1-3-6(7)5-8(9)11/h1-4,8-9,11H,5,10H2/t8-,9+/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
(1S,2R)-1-Amino-2-indanol Dilution Calculator
(1S,2R)-1-Amino-2-indanol Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 6.7114 mL | 33.557 mL | 67.1141 mL | 134.2282 mL | 167.7852 mL |
| 5 mM | 1.3423 mL | 6.7114 mL | 13.4228 mL | 26.8456 mL | 33.557 mL |
| 10 mM | 0.6711 mL | 3.3557 mL | 6.7114 mL | 13.4228 mL | 16.7785 mL |
| 50 mM | 0.1342 mL | 0.6711 mL | 1.3423 mL | 2.6846 mL | 3.3557 mL |
| 100 mM | 0.0671 mL | 0.3356 mL | 0.6711 mL | 1.3423 mL | 1.6779 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Asymmetric synthesis of chiral primary amines by transfer hydrogenation of N-(tert-butanesulfinyl)ketimines.[Pubmed:20617835]
J Org Chem. 2010 Aug 6;75(15):5265-70.
The diastereoselective reduction of (R)-N-(tert-butanesulfinyl)ketimines by a ruthenium-catalyzed asymmetric transfer hydrogenation process in isopropyl alcohol, followed by desulfinylation of the nitrogen atom, is an excellent method to prepare highly enantiomerically enriched alpha-branched primary amines (up to >99% ee) in short reaction times (1-4 h). (1S,2R)-1-Amino-2-indanol has been shown to be a very efficient ligand to perform this transformation. Ketimines bearing either an aryl or a heteroaryl group and an alkyl group as substituents of the iminic carbon atom are very good substrates for this process. The reduction of a dialkyl ketimine could also be achieved, affording the expected amine with moderate optical purity (69% ee). Some amines which are precursors of very interesting biologically and pharmacologically active compounds have been prepared in excellent yields and enantiomeric excesses.
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