TATU

CAS# 873798-09-5

TATU

Catalog No. BCC2822----Order now to get a substantial discount!

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Chemical structure

TATU

3D structure

Chemical Properties of TATU

Cas No. 873798-09-5 SDF Download SDF
PubChem ID 11099301 Appearance Powder
Formula C10H15BF4N6O M.Wt 322.1
Type of Compound N/A Storage Desiccate at -20°C
Solubility Soluble in water or 1% acetic acid
Chemical Name [dimethylamino(triazolo[4,5-b]pyridin-3-yloxy)methylidene]-dimethylazanium;tetrafluoroborate
SMILES [B-](F)(F)(F)F.CN(C)C(=[N+](C)C)ON1C2=C(C=CC=N2)N=N1
Standard InChIKey AUPDFAPCZZXFMX-UHFFFAOYSA-N
Standard InChI InChI=1S/C10H15N6O.BF4/c1-14(2)10(15(3)4)17-16-9-8(12-13-16)6-5-7-11-9;2-1(3,4)5/h5-7H,1-4H3;/q+1;-1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

TATU Dilution Calculator

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TATU Molarity Calculator

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Preparing Stock Solutions of TATU

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.1046 mL 15.5231 mL 31.0463 mL 62.0925 mL 77.6156 mL
5 mM 0.6209 mL 3.1046 mL 6.2093 mL 12.4185 mL 15.5231 mL
10 mM 0.3105 mL 1.5523 mL 3.1046 mL 6.2093 mL 7.7616 mL
50 mM 0.0621 mL 0.3105 mL 0.6209 mL 1.2419 mL 1.5523 mL
100 mM 0.031 mL 0.1552 mL 0.3105 mL 0.6209 mL 0.7762 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on TATU

Crystal structure of the 1,3,6,8-tetra-aza-tri-cyclo[4.3.1.1(3,8)]undecane (TATU)-4-nitro-phenol (1/2) adduct: the role of anomeric effect in the formation of a second hydrogen-bond inter-action.[Pubmed:26594510]

Acta Crystallogr E Crystallogr Commun. 2015 Oct 24;71(Pt 11):1356-60.

In the title ternary co-crystalline adduct, C7H14N4.2C6H5NO3, mol-ecules are linked by two inter-molecular O-Hcdots, three dots, centeredN hydrogen bonds, forming a tricomponent aggregates in the asymmetric unit. The hydrogen-bond formation to one of the N atoms is enough to induce structural stereoelectronic effects in the normal donor-->acceptor direction. In the title adduct, the two independent nitro-phenol mol-ecules are essentially planar, with maximum deviations of 0.0157 (13) and 0.0039 (13) A. The dihedral angles between the planes of the nitro group and the attached benzene rings are 4.04 (17) and 5.79 (17) degrees . In the crystal, aggregates are connected by C-Hcdots, three dots, centeredO hydrogen bonds, forming a supra-molecular dimer enclosing an R 6 (6)(32) ring motif. Additional C-Hcdots, three dots, centeredO inter-molecular hydrogen-bonding inter-actions form a second supra-molecular inversion dimer with an R 2 (2)(10) motif. These units are linked via C-Hcdots, three dots, centeredO and C-Hcdots, three dots, centeredN hydrogen bonds, forming a three-dimensional network.

Mechanochemical synthesis and crystal structure of a 1:2 co-crystal of 1,3,6,8-tetra-aza-tri-cyclo[4.3.1.1(3,8)]undecane (TATU) and 4-chloro-3,5-dimethyl-phenol.[Pubmed:27840729]

Acta Crystallogr E Crystallogr Commun. 2016 Oct 25;72(Pt 11):1651-1653.

Solvent-free treatment of 1,3,6,8-tetra-aza-tri-cyclo-[4.3.1.1(3,8)]undecano (TATU) with 4-chloro-3,5-di-methyl-phenol led to the formation of the title co-crystal, C7H14N4.2C8H9ClO. The asymmetric unit contains one aminal cage mol-ecule and two phenol mol-ecules linked via two O-Hcdots, three dots, centeredN hydrogen bonds. In the aminal cage, the N-CH2-CH2-N unit is slightly distorted from a syn periplanar geometry. Aromatic pi-pi stacking between the benzene rings from two different neighbouring phenol mol-ecules [centroid-centroid distance = 4.0570 (11) A] consolidates the crystal packing.

Crystal structure of the 1:2 co-crystal of 1,3,6,8-tetra-aza-tri-cyclo-[4.3.1.1(3,8)]undecane (TATU) and 4-chloro-phenol (1/2).[Pubmed:27840728]

Acta Crystallogr E Crystallogr Commun. 2016 Oct 25;72(Pt 11):1648-1650.

In the title compound, C7H14N4.2C6H5ClO, which crystallized with two crystallographically independent 4-chloro-phenol mol-ecules and one 1,3,6,8-tetra-aza-tri-cyclo-[4.3.1.1(3,8)]undecane (TATU) mol-ecule in the asymmetric unit, the independent components are linked by two O-Hcdots, three dots, centeredN hydrogen bonds. The hydrogen-bond acceptor sites are two non-equivalent N atoms from the aminal cage structure, and the tricyclic system distorts by changing the C-N bond lengths. In the crystal, these hydrogen-bonded aggregates are linked into chains along the c axis by C-Hcdots, three dots, centeredN hydrogen bonds. The crystal structure also features C-Hcdots, three dots, centeredpi contacts.

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