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apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

CAS# 86546-87-4

apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

Catalog No. BCN8399----Order now to get a substantial discount!

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apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 5mg Please Inquire In Stock
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 10mg Please Inquire In Stock
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 20mg Please Inquire Please Inquire
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 50mg Please Inquire Please Inquire
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 100mg Please Inquire Please Inquire
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 200mg Please Inquire Please Inquire
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 500mg Please Inquire Please Inquire
apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside: 1000mg Please Inquire Please Inquire

Quality Control of apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

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Chemical structure

apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

3D structure

Chemical Properties of apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

Cas No. 86546-87-4 SDF Download SDF
PubChem ID 5487770 Appearance White powder
Formula C24H23O14 M.Wt 535.43
Type of Compound Flavonoids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 3-[5-hydroxy-2-(4-hydroxycyclohexa-2,4-dien-1-yl)-4-oxo-7-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxychromen-3-yl]oxy-3-oxopropanoic acid
SMILES C1=CC(=C[CH]C1C2=C(C(=O)C3=C(C=C(C=C3O2)OC4C(C(C(C(O4)CO)O)O)O)O)OC(=O)CC(=O)O)O
Standard InChIKey ULRLGMUACGKIGP-VKIKYZBHSA-N
Standard InChI InChI=1S/C24H23O14/c25-8-14-18(31)20(33)21(34)24(37-14)35-11-5-12(27)17-13(6-11)36-22(9-1-3-10(26)4-2-9)23(19(17)32)38-16(30)7-15(28)29/h1-6,9,14,18,20-21,24-27,31,33-34H,7-8H2,(H,28,29)/t14-,18-,20+,21-,24-/m1/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Protocol of apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

Structure Identification
Phytochemistry. 2004 Aug;65(16):2323-32.

Isolation, identification and stability of acylated derivatives of apigenin 7-O-glucoside from chamomile (Chamomilla recutita [L.] Rauschert).[Pubmed: 15381003 ]


METHODS AND RESULTS:
The major flavonoids in the white florets of chamomile (Chamomilla recutita [L.] Rauschert) were rapidly purified using a combination of polyamide solid-phase extraction and preparative HPLC. From the combined LC/MS, LC/MS/MS, and NMR data the apigenin glucosides were identified as apigenin 7-O-glucoside (Ap-7-Glc), Ap-7-(6"-malonyl-Glc)(Apigenin 7-O-(6''-O-malonylglucoside) ), Ap-7-(6"-acetyl-Glc), Ap-7-(6"-caffeoyl-Glc), Ap-7-(4"-acetyl-Glc), Ap-7-(4"-acetyl,6"-malonyl-Glc), and a partially characterised apigenin-7-(mono-acetyl/mono-malonylglucoside) isomer. Malonyl and caffeoyl derivatives of Ap-7-Glc have not previously been identified in chamomile.
CONCLUSIONS:
The two mono-acetyl/mono-malonyl flavonoids have not previously been reported in any plant species. These acylated glucosides are unstable and degrade to form acetylated compounds or Ap-7-Glc. The degradation products formed are dependent on the extraction and storage conditions, i.e. temperature, pH and solvent.

apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside Dilution Calculator

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apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside Molarity Calculator

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Preparing Stock Solutions of apigenin 7-O-(6〃-O-malonyl)-β-D-glucoside

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 1.8677 mL 9.3383 mL 18.6766 mL 37.3532 mL 46.6914 mL
5 mM 0.3735 mL 1.8677 mL 3.7353 mL 7.4706 mL 9.3383 mL
10 mM 0.1868 mL 0.9338 mL 1.8677 mL 3.7353 mL 4.6691 mL
50 mM 0.0374 mL 0.1868 mL 0.3735 mL 0.7471 mL 0.9338 mL
100 mM 0.0187 mL 0.0934 mL 0.1868 mL 0.3735 mL 0.4669 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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