6-epi-AlbrassitriolCAS# 178456-58-1 |
- Albrassitriol
Catalog No.:BCN7274
CAS No.:110557-39-6
Quality Control & MSDS
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| Cas No. | 178456-58-1 | SDF | Download SDF |
| PubChem ID | 10015192 | Appearance | Powder |
| Formula | C15H26O3 | M.Wt | 254.37 |
| Type of Compound | Sesquiterpenoids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | (1R,4R,4aS,8aS)-4-(hydroxymethyl)-3,4a,8,8-tetramethyl-5,6,7,8a-tetrahydro-1H-naphthalene-1,4-diol | ||
| SMILES | CC1=CC(C2C(CCCC2(C1(CO)O)C)(C)C)O | ||
| Standard InChIKey | RWPFZPBMMIWKKY-PAPYEOQZSA-N | ||
| Standard InChI | InChI=1S/C15H26O3/c1-10-8-11(17)12-13(2,3)6-5-7-14(12,4)15(10,18)9-16/h8,11-12,16-18H,5-7,9H2,1-4H3/t11-,12+,14+,15-/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
| Description | 6-epi-Albrassitriol is a natural product from A spergillussp. |
| Structure Identification | Nat Prod Res. 2013;27(9):809-17.Synthesis of (-)-albrassitriol and (-)-6-epi-albrassitriol from (+)-larixol.[Pubmed: 22794273 ]A novel synthesis of natural drimanic compounds, (-)-albrassitriol (2) and (-)-6-epi-Albrassitriol (3), has been carried out starting from an easily available labdane diterpenoid, (+)-larixol (1).
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6-epi-Albrassitriol Dilution Calculator
6-epi-Albrassitriol Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 3.9313 mL | 19.6564 mL | 39.3128 mL | 78.6256 mL | 98.282 mL |
| 5 mM | 0.7863 mL | 3.9313 mL | 7.8626 mL | 15.7251 mL | 19.6564 mL |
| 10 mM | 0.3931 mL | 1.9656 mL | 3.9313 mL | 7.8626 mL | 9.8282 mL |
| 50 mM | 0.0786 mL | 0.3931 mL | 0.7863 mL | 1.5725 mL | 1.9656 mL |
| 100 mM | 0.0393 mL | 0.1966 mL | 0.3931 mL | 0.7863 mL | 0.9828 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Synthesis of (-)-albrassitriol and (-)-6-epi-albrassitriol from (+)-larixol.[Pubmed:22794273]
Nat Prod Res. 2013;27(9):809-17.
A novel synthesis of natural drimanic compounds, (-)-albrassitriol (2) and (-)-6-epi-Albrassitriol (3), has been carried out starting from an easily available labdane diterpenoid, (+)-larixol (1). In a two-step procedure, (+)-larixol (1) was converted into 14,15-bisnorlab-7-ene-6,13-dione (9), which was then submitted to a Norrish type II photochemical degradation yielding drim-7,9(11)-diene-6-one (10), whose treatment with OsO4 led selectively to the formation of drim-7-ene-9alpha,11-diol-6-one (12). The same compound was obtained by selective epoxidation of the C(9)-C(11) double bond in drim-7,9(11)-diene-6-one (10) with monoperphtalic acid. Treatment of the resulting mixture of alpha- and beta-epoxides (13 and 14) with HClO4 yielded drim-7-ene-9alpha,11-diol-6-one (12). Reduction of the C6-carbonyl group in drim-7-ene-9alpha,11-diol-6-one (12) with LiAlH4 afforded (-)-albrassitriol (2) and (-)-6-epi-Albrassitriol (3), 12.4% and 13.6% overall yields, respectively.
