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3-Methoxymollugin

CAS# 154706-44-2

3-Methoxymollugin

Catalog No. BCN7164----Order now to get a substantial discount!

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3-Methoxymollugin: 5mg $799 In Stock
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Quality Control of 3-Methoxymollugin

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Chemical structure

3-Methoxymollugin

3D structure

Chemical Properties of 3-Methoxymollugin

Cas No. 154706-44-2 SDF Download SDF
PubChem ID 46187191 Appearance Powder
Formula C18H18O5 M.Wt 314.33
Type of Compound Phenols Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name methyl 6-hydroxy-3-methoxy-2,2-dimethylbenzo[h]chromene-5-carboxylate
SMILES CC1(C(=CC2=C(O1)C3=CC=CC=C3C(=C2C(=O)OC)O)OC)C
Standard InChIKey OCQKAHAAVZGZPO-UHFFFAOYSA-N
Standard InChI InChI=1S/C18H18O5/c1-18(2)13(21-3)9-12-14(17(20)22-4)15(19)10-7-5-6-8-11(10)16(12)23-18/h5-9,19H,1-4H3
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of 3-Methoxymollugin

The roots of Pentas longiflora.

Biological Activity of 3-Methoxymollugin

Description1. 3-Methoxymollugin is a cytotoxic compound.

3-Methoxymollugin Dilution Calculator

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3-Methoxymollugin Molarity Calculator

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Preparing Stock Solutions of 3-Methoxymollugin

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.1814 mL 15.9068 mL 31.8137 mL 63.6274 mL 79.5342 mL
5 mM 0.6363 mL 3.1814 mL 6.3627 mL 12.7255 mL 15.9068 mL
10 mM 0.3181 mL 1.5907 mL 3.1814 mL 6.3627 mL 7.9534 mL
50 mM 0.0636 mL 0.3181 mL 0.6363 mL 1.2725 mL 1.5907 mL
100 mM 0.0318 mL 0.1591 mL 0.3181 mL 0.6363 mL 0.7953 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 3-Methoxymollugin

New pyranonaphthoquinone and pyranonaphthohydroquinone from the roots of Pentas longiflora.[Pubmed:12350172]

J Nat Prod. 2002 Sep;65(9):1377-9.

Several quinone type compounds were isolated from the hexane, dichloromethane, and ethyl acetate extracts of the roots of Pentas longiflora. The hexane extract afforded two new compounds, [(3alpha,3'alpha,4beta,4'beta)-3,3']-dimethoxy-cis-[4,4'-bis(3,4,5,10-tetrahydro- 1H-naphtho[2,3-c]pyran)]-5,5',10,10'-tetraone (1) and cis-3,4-dihydroxy-3,4-dihydromollugin (2), together with six known compounds, namely, pentalongin, mollugin, trans-3,4-dihydroxy-3,4-dihydromollugin, methyl-2,3-epoxy-3-prenyl-1,4-naphthoquinone-2-carboxylate, tectoquinone, and 3-hydroxymollugin. From the dichloromethane extract were isolated the three known compounds 3-Methoxymollugin, methyl-3-prenyl-1,4-naphthoquinone-2-carboxylate, and scopoletin, while the ethyl acetate extract afforded the known 2-methoxy-3-methylanthraquinone.

Synthesis of the natural products 3-hydroxymollugin and 3-methoxymollugin.[Pubmed:20201485]

J Org Chem. 2010 Apr 2;75(7):2274-80.

3-Hydroxymollugin 2 and 3-Methoxymollugin 3 are cytotoxic compounds isolated as minor compounds from Pentas longiflora and Rubia cordifolia. Syntheses of 3-hydroxymollugin 2 and 3-Methoxymollugin 3 were developed starting from easily available 3-bromomollugin 6. Surprisingly, it was found that the reaction of 3-bromomollugin 6 with sodium methoxide in methanol resulted in the formation of 3-Methoxymollugin 3 and the ring-contracted methyl isopropenylfuromollugin 7. A mechanism for this ring contraction is proposed on the basis of a pericyclic retro oxa-6pi ring-opening reaction. A second synthesis of 3-hydroxymollugin 2 was based on epoxidation of methyl 3-(3-methylbut-2-enyl)-1,4-naphthoquinone-2-carboxylate 17 and subsequent reduction of the quinone moiety, ring transformation, and DDQ oxidation. The latter oxidation process results in 3-hydroxymollugin 2 along with the rearranged furomollugin 4, which is a ring-contracted analogue of the natural product mollugin 1.

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