LaburnineCAS# 3348-73-0 |
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Quality Control & MSDS
3D structure
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| Cas No. | 3348-73-0 | SDF | Download SDF |
| PubChem ID | 94259 | Appearance | Oil |
| Formula | C8H15NO | M.Wt | 141.21 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | [(1S,8R)-2,3,5,6,7,8-hexahydro-1H-pyrrolizin-1-yl]methanol | ||
| SMILES | C1CC2C(CCN2C1)CO | ||
| Standard InChIKey | LOFDEIYZIAVXHE-HTQZYQBOSA-N | ||
| Standard InChI | InChI=1S/C8H15NO/c10-6-7-3-5-9-4-1-2-8(7)9/h7-8,10H,1-6H2/t7-,8-/m1/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
| Structure Identification | J Org Chem. 1999 Apr 30;64(9):3122-3131.Enamino Ester Reduction: A Short Enantioselective Route to Pyrrolizidine and Indolizidine Alkaloids. Synthesis of (+)-Laburnine, (+)-Tashiromine, and (-)-Isoretronecanol.[Pubmed: 11674411]
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Laburnine Dilution Calculator
Laburnine Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 7.0817 mL | 35.4083 mL | 70.8165 mL | 141.633 mL | 177.0413 mL |
| 5 mM | 1.4163 mL | 7.0817 mL | 14.1633 mL | 28.3266 mL | 35.4083 mL |
| 10 mM | 0.7082 mL | 3.5408 mL | 7.0817 mL | 14.1633 mL | 17.7041 mL |
| 50 mM | 0.1416 mL | 0.7082 mL | 1.4163 mL | 2.8327 mL | 3.5408 mL |
| 100 mM | 0.0708 mL | 0.3541 mL | 0.7082 mL | 1.4163 mL | 1.7704 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Enamino Ester Reduction: A Short Enantioselective Route to Pyrrolizidine and Indolizidine Alkaloids. Synthesis of (+)-Laburnine, (+)-Tashiromine, and (-)-Isoretronecanol.[Pubmed:11674411]
J Org Chem. 1999 Apr 30;64(9):3122-3131.
Various chiral pyrrolidine tetrasubstituted beta-enamino esters were reduced catalytically or chemically with good to moderate diastereoselectivity owing to a chiral induction originated from (S)-alpha-methylbenzylamine. With endocyclic double bond compounds, the best result was obtained using PtO(2) as hydrogenation catalyst and led to a major syn addition product (e.d. 90%). In the case of exocyclic double bond compounds, hydrogenation over Pd/C gave rise to the higher diastereoselectivity and mainly afforded the unexpected anti addition product (e.d. 84%). The scope of these reductions has been extended to the synthesis of three pyrrolizidine or indolizidine alkaloids: (+)-tashiromine, (+)-Laburnine, and (-)-isoretronecanol. Syntheses of these natural products, starting from chiral beta-enamino diesters, were achieved in a short and convenient manner, leading to enantiopure compounds in good overall yields.
