16-EpivoacarpineCAS# 114027-38-2 |
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| Cas No. | 114027-38-2 | SDF | Download SDF |
| PubChem ID | 13946382 | Appearance | Powder |
| Formula | C21H24N2O4 | M.Wt | 368.4 |
| Type of Compound | Alkaloids | Storage | Desiccate at -20°C |
| Solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | ||
| Chemical Name | methyl (1R,12S,13R,14S,15E)-15-ethylidene-1-hydroxy-13-(hydroxymethyl)-3,17-diazapentacyclo[12.3.1.02,10.04,9.012,17]octadeca-2(10),4,6,8-tetraene-13-carboxylate | ||
| SMILES | CC=C1CN2C3CC4=C(C2(CC1C3(CO)C(=O)OC)O)NC5=CC=CC=C45 | ||
| Standard InChIKey | ZROBSNVANUBAJZ-LWKNIGJSSA-N | ||
| Standard InChI | InChI=1S/C21H24N2O4/c1-3-12-10-23-17-8-14-13-6-4-5-7-16(13)22-18(14)21(23,26)9-15(12)20(17,11-24)19(25)27-2/h3-7,15,17,22,24,26H,8-11H2,1-2H3/b12-3-/t15-,17-,20+,21+/m0/s1 | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
| Description | 16-Epivoacarpine is a natural product from Gelsemium elegans. |
| Structure Identification | Studies in Natural Products Chemistry, 1995 , 15 (06) :465-518.Recent advances in the chemistry of Gelsemium alkaloids.[Reference: WebLink]This chapter reviews the recent intensive research that led to significant progress in the field of Gelsemium alkaloid chemistry. It presents alkaloids isolated from the Gelsemium species.
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16-Epivoacarpine Dilution Calculator
16-Epivoacarpine Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 2.7144 mL | 13.5722 mL | 27.1444 mL | 54.2888 mL | 67.861 mL |
| 5 mM | 0.5429 mL | 2.7144 mL | 5.4289 mL | 10.8578 mL | 13.5722 mL |
| 10 mM | 0.2714 mL | 1.3572 mL | 2.7144 mL | 5.4289 mL | 6.7861 mL |
| 50 mM | 0.0543 mL | 0.2714 mL | 0.5429 mL | 1.0858 mL | 1.3572 mL |
| 100 mM | 0.0271 mL | 0.1357 mL | 0.2714 mL | 0.5429 mL | 0.6786 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Recent advances in the chemistry of Gelsemium alkaloids.
Studies in Natural Products Chemistry, 1995 , 15 (06) :465-518.
This chapter reviews the recent intensive research that led to significant progress in the field of Gelsemium alkaloid chemistry. It presents alkaloids isolated from the Gelsemium species. The structure elucidation of the representative alkaloids using mainly spectroscopic methods is described. The chapter discusses the biogenetic speculation of the structurally unique Gelsemium alkaloids and the biomimetic transformation of the known indole alkaloids leading to the various skeletal types of Gelsemium alkaloids. A genuine indole nucleus is present only in the sarpagine group and sempervirine among the many skeletal classes of the Gelsemium alkaloids. The sarpagine group found in the Gelsemium species consists of six indole alkaloids, 19( Z )-akuammidine (koumicine), koumicine N -oxide, koumidine, 16-Epivoacarpine, 19(Z)-anhydrovobasine-diol, and N a -methoxy-19( Z )-anhydrovobasinediol. The structure elucidation of the indole alkaloid, the so-called akuammidine isolated from Gelsemium elegans is discussed in the chapter. The configuration of the ethylidene side chain was considered the 19( E ) form as generally found in the monoterpenoid indole alkaloids. The so-called akuammidine from G. elegans showed the same mass spectral fragment pattern as authentic akuammidine obtained from other plant sources.
