Home >> Research Area >>Natural Products>>Alkaloids>> N-Methylsarpagine methosalt

N-Methylsarpagine methosalt

CAS# 47418-70-2

N-Methylsarpagine methosalt

Catalog No. BCN5530----Order now to get a substantial discount!

Product Name & Size Price Stock
N-Methylsarpagine methosalt: 5mg Please Inquire In Stock
N-Methylsarpagine methosalt: 10mg Please Inquire In Stock
N-Methylsarpagine methosalt: 20mg Please Inquire Please Inquire
N-Methylsarpagine methosalt: 50mg Please Inquire Please Inquire
N-Methylsarpagine methosalt: 100mg Please Inquire Please Inquire
N-Methylsarpagine methosalt: 200mg Please Inquire Please Inquire
N-Methylsarpagine methosalt: 500mg Please Inquire Please Inquire
N-Methylsarpagine methosalt: 1000mg Please Inquire Please Inquire

Quality Control of N-Methylsarpagine methosalt

Number of papers citing our products

Chemical structure

N-Methylsarpagine methosalt

3D structure

Chemical Properties of N-Methylsarpagine methosalt

Cas No. 47418-70-2 SDF Download SDF
PubChem ID 75492733 Appearance Powder
Formula C21H27N2O2 M.Wt 339.5
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name (1S,12S,13R,14R,15E)-15-ethylidene-13-(hydroxymethyl)-3,17-dimethyl-3-aza-17-azoniapentacyclo[12.3.1.02,10.04,9.012,17]octadeca-2(10),4(9),5,7-tetraen-7-ol
SMILES CC=C1C[N+]2(C3CC1C(C2CC4=C3N(C5=C4C=C(C=C5)O)C)CO)C
Standard InChIKey JTTRGCDSKZRQPP-PRQFWUQUSA-O
Standard InChI InChI=1S/C21H26N2O2/c1-4-12-10-23(3)19-9-16-15-7-13(25)5-6-18(15)22(2)21(16)20(23)8-14(12)17(19)11-24/h4-7,14,17,19-20,24H,8-11H2,1-3H3/p+1/b12-4-/t14-,17+,19-,20-,23?/m0/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of N-Methylsarpagine methosalt

The roots of Alstonia yunnanensis Diels

Protocol of N-Methylsarpagine methosalt

Structure Identification
Journal of organic chemistry, 2003, 34(49):6279.

The enantiospecific, stereospecific total synthesis of the ring-A oxygenated sarpagine indole alkaloids (+)-majvinine, (+)-10-methoxyaffinisine, and (+)-N(a)-methylsarpagine, as well as the total synthesis of the alstonia bisindole alkaloid macralstonidin[Pubmed: 12895062 ]


METHODS AND RESULTS:
The first stereospecific, enantiospecific total synthesis of the ring-A oxygenated sarpagine indole alkaloids (+)-N(a)-methylsarpagine (N-Methylsarpagine methosalt, 8), (+)-majvinine (14), and (+)-10-methoxyaffinisine (49), as well as the first total synthesis of the Alstonia bisindole alkaloid macralstonidine (9), has been accomplished. This approach employed the Schöllkopf chiral auxiliary for the stereospecific construction of the desired d-(+)-tryptophan unit required for the asymmetric Pictet-Spengler reaction. In addition, the strategy was doubly convergent for the enolate-mediated Pd(0) coupling process and the asymmetric Pictet-Spengler reaction can be employed to synthesize both macroline (2) and N(a)-methylsarpagine (8), the coupling of which provides macralstonidine (9).
CONCLUSIONS:
This approach to ring-A substituted alkoxyindole alkaloids should find wide application for the synthesis of other alkaloids for it is stereospecific and either enantiomer can be prepared with ease.

N-Methylsarpagine methosalt Dilution Calculator

Concentration (start)
x
Volume (start)
=
Concentration (final)
x
Volume (final)
 
 
 
C1
V1
C2
V2

calculate

N-Methylsarpagine methosalt Molarity Calculator

Mass
=
Concentration
x
Volume
x
MW*
 
 
 
g/mol

calculate

Preparing Stock Solutions of N-Methylsarpagine methosalt

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.9455 mL 14.7275 mL 29.4551 mL 58.9102 mL 73.6377 mL
5 mM 0.5891 mL 2.9455 mL 5.891 mL 11.782 mL 14.7275 mL
10 mM 0.2946 mL 1.4728 mL 2.9455 mL 5.891 mL 7.3638 mL
50 mM 0.0589 mL 0.2946 mL 0.5891 mL 1.1782 mL 1.4728 mL
100 mM 0.0295 mL 0.1473 mL 0.2946 mL 0.5891 mL 0.7364 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

Organizitions Citing Our Products recently

 
 
 

Calcutta University

University of Minnesota

University of Maryland School of Medicine

University of Illinois at Chicago

The Ohio State University

University of Zurich

Harvard University

Colorado State University

Auburn University

Yale University

Worcester Polytechnic Institute

Washington State University

Stanford University

University of Leipzig

Universidade da Beira Interior

The Institute of Cancer Research

Heidelberg University

University of Amsterdam

University of Auckland
TsingHua University
TsingHua University
The University of Michigan
The University of Michigan
Miami University
Miami University
DRURY University
DRURY University
Jilin University
Jilin University
Fudan University
Fudan University
Wuhan University
Wuhan University
Sun Yat-sen University
Sun Yat-sen University
Universite de Paris
Universite de Paris
Deemed University
Deemed University
Auckland University
Auckland University
The University of Tokyo
The University of Tokyo
Korea University
Korea University
Featured Products
New Products
 

Keywords:

N-Methylsarpagine methosalt,47418-70-2,Natural Products, buy N-Methylsarpagine methosalt , N-Methylsarpagine methosalt supplier , purchase N-Methylsarpagine methosalt , N-Methylsarpagine methosalt cost , N-Methylsarpagine methosalt manufacturer , order N-Methylsarpagine methosalt , high purity N-Methylsarpagine methosalt

Online Inquiry for:

      Fill out the information below

      • Size:Qty: - +

      * Required Fields

                                      Result: