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14-Dehydrobrowniine

CAS# 4829-56-5

14-Dehydrobrowniine

Catalog No. BCN8109----Order now to get a substantial discount!

Product Name & Size Price Stock
14-Dehydrobrowniine: 5mg $989 In Stock
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Quality Control of 14-Dehydrobrowniine

Number of papers citing our products

Chemical structure

14-Dehydrobrowniine

3D structure

Chemical Properties of 14-Dehydrobrowniine

Cas No. 4829-56-5 SDF Download SDF
PubChem ID 165269 Appearance Powder
Formula C25H39NO7 M.Wt 465.57
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one
SMILES CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6=O)OC)O)O)OC)OC)COC
Standard InChIKey MWOQLGAENOKSHS-UHFFFAOYSA-N
Standard InChI InChI=1S/C25H39NO7/c1-6-26-11-22(12-30-2)8-7-16(32-4)24-14-9-13-15(31-3)10-23(28,17(14)18(13)27)25(29,21(24)26)20(33-5)19(22)24/h13-17,19-21,28-29H,6-12H2,1-5H3
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of 14-Dehydrobrowniine

The roots of Delphinium stapeliosum

Protocol of 14-Dehydrobrowniine

Structure Identification
Chemical & Pharmaceutical Bulletin, 2009, 35(6):2615-2617.

STRUCTURES OF TOROKONINE AND GOMANDONINE, TWO NEW DITERPENE ALKALOIDS FROM ACONITUM SUBCUNEATUM NAKAI[Reference: WebLink]


METHODS AND RESULTS:
Chemical investigation of the roots of Aconitum subcuneatum Nakai resulted in the isolation of two new diterpene alkaloids torokonine (1) and gomandonine (2), along with eight known compounds, i.e. mesaconitine, jesaconitine, 14-Dehydrobrowniine, neoline, 15-α-hydroxyneoline, isotalatizidine, senbusine A, and virescenine. The structure and the absolute configuration of torokonine (1) were established as 7-α-hydroxy ryosenamine from the spectroscopic analysis.
CONCLUSIONS:
The novel structure of gomandonine (2), having an epoxy ring, was initially deduced by the pyridine-induced solvent shift technique and then confirmed by X-ray analysis.

14-Dehydrobrowniine Dilution Calculator

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14-Dehydrobrowniine Molarity Calculator

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Preparing Stock Solutions of 14-Dehydrobrowniine

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.1479 mL 10.7395 mL 21.479 mL 42.9581 mL 53.6976 mL
5 mM 0.4296 mL 2.1479 mL 4.2958 mL 8.5916 mL 10.7395 mL
10 mM 0.2148 mL 1.074 mL 2.1479 mL 4.2958 mL 5.3698 mL
50 mM 0.043 mL 0.2148 mL 0.4296 mL 0.8592 mL 1.074 mL
100 mM 0.0215 mL 0.1074 mL 0.2148 mL 0.4296 mL 0.537 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 14-Dehydrobrowniine

STRUCTURES OF TOROKONINE AND GOMANDONINE, TWO NEW DITERPENE ALKALOIDS FROM ACONITUM SUBCUNEATUM NAKAI

Chemical & Pharmaceutical Bulletin, 2009, 35(6):2615-2617.

Chemical investigation of the roots of Aconitum subcuneatum Nakai resulted in the isolation of two new diterpene alkaloids torokonine (1) and gomandonine (2), along with eight known compounds, i.e. mesaconitine, jesaconitine, 14-Dehydrobrowniine, neoline, 15-α-hydroxyneoline, isotalatizidine, senbusine A, and virescenine. The structure and the absolute configuration of torokonine (1) were established as 7-α-hydroxy ryosenamine from the spectroscopic analysis. The novel structure of gomandonine (2), having an epoxy ring, was initially deduced by the pyridine-induced solvent shift technique and then confirmed by X-ray analysis.

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